-2010- 

118. Assembling Discrete D4R Zeolite SBUs through Noncovalent Interactions. 3. Mediation by Butanols and 1,2-

       Bis(dimethylamino)ethane. 
       R. Murugavel*, S. Kuppuswamy, N. Gogoi, and A. Steiner, 

       Inorg. Chem., 2010, 49, 2153-2162.

​

117. Noncovalent Synthesis of Hierarchical Zinc Phosphates from a Single Zn4O12P4Double-Four-Ring Building Block: Dimensionality

       Control through the Choice of Auxiliary Ligands. 
       R. Murugavel*, S. Kuppuswamy, N. Gogoi, R. Boomishankar and A. Steiner, 

       Chem. Euro. J., 2010, 16, 994-1009.

116. Three-dimensional sodium phosphinates derived from a bis-functionalized phosphinic acid. 
       R. Murugavel*, S. Shanmugan and N. Gogoi, 

       Inorg. Chem. Commun., 2010, 13, 1530-1533.

115. A hexanuclear iron(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2]•3CH33CN assembled from 2-hydroxyethyl-3,5-dimethylpyrazole. 
       R. Murugavel*, N. Gogoi and R. Clerac, 

       Inorg. Chim. Acta, 2010, 363, 3004-3009.  (Dedicated to Prof. Animesh Chakravorty on his 75th Birthday)

114. One, two, and three methylene phosphonic acid groups (-CH2PO3H2) on a mesitylene ring: synthesis,characterization and aspects of

       supramolecular aggregation. 
       R. Murugavel* and M.P. Singh 

       New. J. Chem., 2010, 34, 1846-1854.

113. Rings, chains and cages in metal phosphate chemistry: The interdependence and possible interconversion between various

       structural forms. 
       R. Murugavel* and N. Gogoi                   

       . Organomet. Chem., 2010, 695, 916-924.

​

-2009-

112. Structural variations in layered alkaline earth metal cyclohexyl phosphonates. 
       R. Murugavel* and N. Gogoi, 

       Bull. Mater. Sci. 2009, 32, 321-328.

111. Nuclearity control in molecular iron phosphates through choice of iron precursors and ancillary ligands. 
       R. Murugavel* and N. Gogoi, 

       Chem. Asian. J., 2009, 4, 923-935. 

110. Solving Zeolite Jigsaw through Coordination Chemistry
       R. Murugavel* and M. P. Singh

       In a Book "Insights into Coordination, Bioinorganic and Applied Inorganic Chemistry"

       Press of Slovak University of Technology, Bratislava,  2009, 211-220.

109. Conformational and Isomeric Preferences of Six-Membered Inorganic Heterocycles [EtNP(E)(OR)]3 (E = Lone Pair, O, S, or Se): A

        Synthetic, Spectroscopic, Structural, and Computational Study. 
        R. Murugavel*, G. Prabusankar, R.J. Butcher, A. Sharma and R.B. Sunoj,  

        Inorg.Chem. 2009, 48, 2048-2059.

108. Tetra- and Decanuclear Iron(III) Phosphonates: Observance of a Rare P-C Bond Cleavage in a Homogeneous Medium. 
        R. Murugavel*, N. Gogoi and R. Clerac, 

        Inorg. Chem., 2009, 48, 646-651.

107. Di-, Tri-, Tetra-, and Hexanuclear Copper(II) Mono-organophosphates: Structure and Nuclearity Dependenceon the Choice of

        Phosphorus Substituents and Auxiliary N-Donor Ligands. 
        R. Murugavel*, S. Kuppuswamy, A.N. Maity and M.P. Singh, 

        Inorg. Chem., 2009, 48, 183-192. 

106. Controlling the structure of manganese(II) phosphates by the choice and ratio of organophosphate and auxiliary ligands. 
        R. Murugavel*, S. Kuppuswamy, N. Gogoi, A. Steiner and J Bacsa, R. Boomishankar and K.G. Suresh, 

        Chem. Asian. J., 2009, 4, 143-153.

-2008-

105. Assembling metal phosphonates in the presence of monodentate-terminal and bidentate-bridging pyridine ligands. Use of non-

        covalent and covalent-coordinate interactions to build polymeric metal-phosphonate architectures. 
        R. Murugavel* and S. Shanmugan 

        Dalton Trans., 2008, 39, 5358-5367.

104. Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure,Transformations, and

        Applications. 
        R. Murugavel*, A. Choudhury, M. G. Walawalkar, R. Pothiraja, C. N. R. Rao* 

        Chem.Rev. 2008, 108, 3549-3655.

103. Microwave assisted solid-state synthesis of functional organotin carboxylates from sterically encumbered 3,5-di-tert-butylsalicylic           acid. 
        R. Murugavel* and N. Gogoi 

        J. Organomet. Chem., 2008, 693, 3111-3116.

102. Organic-Soluble Tri-, Tetra-, and Pentanuclear Titanium(IV) Phosphates. 
        R. Murugavel* and S. Kuppuswamy 

        Inorg. Chem., 2008, 47, 7686-7694.

101.  Cooperative Binding of Phosphate Anion and a Neutral Nitrogen Donor to Alkaline-Earth Metal Ions.Investigation of Group 2 Metal-           Organophosphate Interaction in the Absence and Presence of 1,10-Phenanthroline. 
        R. Murugavel*, S. Kuppuswamy and S. Randoll 

        Inorg. Chem., 2008, 47, 6028-6039.

100. Asymmetric pentameric and tetrameric organooxotin clusters: insights into their formation through partial dearylation. 
        R. Murugavel* and S. Shanmugan

        Organometallics, 2008, 27, 2784-2788.

99.   Water in organoaluminum chemistry! Three-in-one aluminophosphate clusters that incorporate boehmite repeating units. 
        R. Murugavel* and S. Kuppuswamy 

        Chem. Euro. J., 2008, 14, 3869-3873. 

98.   Structural diversity in zinc phosphates and phosphinates: observation of a lattice water dimer sandwiched between phosphoryl

        oxygen atoms. 
        R. Pothiraja, S. Shanmugan, M. G. Walawalkar, M. Nethaji, R.J. Butcher and R. Murugavel*

        Eur. J. Inorg. Chem., 2008, 11, 1834-1845. 

97.   Structural diversity in organotin compounds derived from bulky monoaryl phosphates: dimeric, tetrameric, and polymeric tin      

        phosphate complexes. 
        R. Murugavel*, S. Shanmugan and S. Kuppuswamy 

        Eur. J. Inorg. Chem., 2008, 9, 1508-1517. 

96.   Facile one-pot synthesis of functionalized organophosphonate esters via ketone insertion into bulky aryl phosphites. 
        R. Murugavel* and S. Kuppuswamy 

        J. Chem. Sci. , 2008, 120, 131-136. 
 

-2007-

95.   Structural Diversity and Supramolecular Aggregation in Calcium, Strontium, and Barium Salicylates Incorporating 1,10-

        Phenanthroline and 4,4'-Bipyridine: Probing the Softer Side of Group 2 Metal Ions with Pyridinic Ligands. 
        R. Murugavel* and R. Korah 

        Inorg. Chem., 2007, 46, 11408-11062.

94.   Supramolecular Aggregation in Alkaline Earth Metal Amino Benzoates with 1,10-Phenanthroline Auxiliary. 
        R. Murugavel* and R. Korah

        Synth. React. Inorg. Met.-Org. Chem. Nano-Met. Chem., 2007, 37, 779-795.

93.   A Double Helix Is the Repeating Unit in a Luminescent Calcium 5-Aminoisophthalate Supramolecular Edifice with Water-Filled  

        Hexagonal Channels. 
        R. Murugavel*, P. Kumar, M. G. Walawalkar and R. Mathialagan 

        Inorg. Chem., 2007, 46, 6828-6830.  

92.   Unusual reactivity of a sterically hindered diphosphazane ligand, EtN{P(OR)2}2, (R = C6H3(Pri)2-2,6) towards (h3-allyl)palladium

        precursors. 
        H. Krishna, S.S. Krishnamurthy, M. Nethaji, R. Murugavel* and G. Prabusankar 

        Dalton Trans., 2007, 27, 2908-2914.

91.   Synthesis, magnetic behaviour, and X-ray structures of dinuclear copper complexes with multiple bridges.Efficient and selective

       catalysts for polymerization of 2,6-dimethylphenol. 
       R. Murugavel*, R. Pothiraja, N. Gogoi, R. Clerac, L. Lecren, R.J. Butcher, M. Nethaji 

       Dalton Trans., 2007, 23, 2405-2410.

90.  Cobalt-5-aminoisophthalate: [Co(AIPA)(OH2)2]n•nH2O: a new one-dimensional rail-road polymer with occluded water

       molecules. 
       S. Banerjee, S. Shanmugan and R. Murugavel* 

       Struct. Chem., 2007, 18, 165-169.

89.  First organotin complex of a phosphonic diamide RP(O)(NHR)2. 
       R. Murugavel*, R. Pothiraja, S. Shanmugan, N. Singh, R.J. Butcher 

       J. Organomet. Chem., 2007, 692, 1920-1923. 

88.  Seeking tetrameric transition metal phosphonate with a D4R core and organizing it into a 3-D supramolecular assembly. 
       R. Murugavel* and S. Shanmugan 

       Chem. Comm., 2007, 12, 1257-1259.

​

-2006-

87.  Novel Layered Copper Phosphoramidate, Which Contains Six-Membered Rings Made of Five Different Elements 
       R. Murugavel* and M.P. Singh  

       Inorg. Chem., 2006, 45, 9154-9156.
      
86.  Octameric and decameric aluminophosphates 
       R. Murugavel* and S. Kuppuswamy 

       Angew.Chem., Int.Ed., 2006, 45, 7022-7026.

85.  A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu2(HSal)(Sal)(2,2'-bpy)2]

       (ClO4) 
       N. Palanisami, G. Prabusankar and R. Murugavel* 

       Inorg. Chem. Commun., 2006, 9, 1002-1006.

84.  Hierarchical structures built form a molecular zinc phosphate core 
       R. Murugavel*, S. Kuppuswamy, R. Boomishankar and A. Steiner

       Angew. Chem., Int.Ed., 2006, 45, 5536-5540.

83.  Synthesis and spectral characterization of diorganodiaminosilanes [(ArNH)2SiPhMe] (Ar = 2,6-iPr2C6H3; 2,4,6-Me3C6H2) and lithium          silylamide [(2,6-Et2C6H3NLi)(2,6-Et2C6H3NH)SiPh2] 
       N. Palanisami and R. Murugavel* 

       J. Organomet. Chem., 2006, 691, 3260-3266.

82.  Sterically encumbered acyclic diphosphazanes: synthesis, conformations and coordination behavior 
       G. Prabusankar, N. Palanisami, R. Murugavel* and R.J. Butcher 

       Dalton Trans., 2006, 17, 2140-2146. 
 

-2005-

81.  First examples of metal cyclohexylphosphonates: influence of the choice of synthetic route on the product 
       R. Murugavel*, P. Davis and M. G. Walawalkar 

       Z. Anorg. Allg. Chem., 2005, 631, 2806-2811.

80.  Recent developments in the chemistry of molecular titanosiloxanes and titanophosphonates 
       P. Davis and R. Murugavel* 

       Synth. React. Inorg. Met.-Org. Chem. Nano-Met. Chem., 2005, 35, 591-622. 

79.  Non-Interpenetrating Transition Metal Diorganophosphate 2-Dimensional Rectangular Grids from Their 1- Dimensional Wires:

       Structural Transformations under Mild Conditions 
       R. Pothiraja, M. Sathiyendiran, R.J. Butcher and R. Murugavel* 

       Inorg. Chem., 2005, 44, 6314-6323.

78.  Synthesis, Spectral Studies, and Structural Characterization of a New Organosilanetriol, Its Amine Complexes, and a Surface Lewis              Basic Cubic Aluminosilicate
       G. Prabusankar, R. Murugavel* and R.J. Butcher 

       Organometallics, 2005, 24, 2124-2128. 

​

-2004-

77.  Cobalt and Manganese Nets via Their Wires: Facile Transformation in Metal-Diorganophosphates 
       R. Pothiraja, M. Sathiyendiran, R.J. Butcher and R. Murugavel* 

       Inorg.Chem., 2004, 43, 7585-7587. 

76.  Hexameric Organotincarboxylates with Cyclic and Drum Structures 
       G. Prabusankar and R. Murugavel* 

       Organometallics 2004, 23, 5644-5647. 

75.  Transformations of Molecules and Secondary Building Units to Materials: A Bottom-Up Approach 
       R. Murugavel*, M. G. Walawalkar, M. Dan, H. W. Roesky* and C. N. R. Rao* 

       Acc.Chem.Res. 2004, 37, 763-774.

74.  ATP Synthase and the Torsional Mechanism: Resolving a 50-Yeal-Old Mystery. 
       S. Jain, R. Murugavel* and L D. Hansen 

       Curr. Sci., 2004, 87, 16-19 

73.  Polyhedral ferrous and ferric siloxanes 
       U.N. Nehete, G. Anantharaman, V. Chandrasekhar, R. Murugavel*, M.G. Walawalkar, H. W. Roesky* , D. Vidovic, J. Magull, K. Samwer

       and B. Sass 

       Angew. Chem., Int. Ed., 2004, 43, 3832-3835. 

72.  Formation of One-Dimensional Water Inside an Organic Solid: Supramolecular Architectures Derived by the Interaction of      

       Aminobenzoic Acids with Nitrogen Bases and H2SO4 
       S. Banerjee and R. Murugavel* 

       Cryst. Growth Des., 2004, 4, 545-552. 

71.   Stabilization of Organosilanetriols in Amine Matrices: Trapping Intermediates between RSi(OH)3 and (RSiO3)3- Anions 
       G. Prabusankar, R. Murugavel* and R.J. Butcher

       Organometallics, 2004, 23, 2305-2314. 

70.  Monomeric, Tetrameric, and Polymeric Copper Di-tert-butyl Phosphate Complexes Containing Pyridine Ancillary Ligands 
       R. Murugavel*, M. Sathiyendiran, R. Pothiraja, M. G. Walawalkar, T. Mallah and E. Riviere, 

       Inorg. Chem., 2004, 43, 945-953. 

69.  Stabilization of p-block organoelement terminal hydroxides, thiols, and selenols requires newer synthetic strategies 
       H. W. Roesky*, R. Murugavel and M. G. Walawalkar 

       Chem. Euro. J., 2004, 10, 324-331.

-2003-

68.  O-H Bond elongation in co-ordinated water through intramolecular P:O•••H-O bonding. Snap-shots' in phosphate ester hydrolysis 
       R. Murugavel*, M. Sathiyendiran, R. Pothiraja and R.J. Butcher 

       Chem. Commun.,  2003, 20, 2546-2547 DOI :10.1039/b306038a

67.  A nanoscopic molecular cadmium phosphonate wrapped in a hydrocarbon sheath 
       G. Anantharaman, M. G. Walawalkar, R. Murugavel, B. Gabor, R. Herbst-Irmer, M. Baldus, B. Angerstein, H. W. Roesky* 

       Angew. Chem., Int.Ed., 2003, 42, 4482-4485 DOI :10.1002/anie.200352133

66.  Reactions of 1,3,5-Benzenetricarboxylic acid with Zn(II) ion in the presence of added amines: Isolation and structure determination

       of zinc coordination polymers with tetrahedral and octahedral zinc centres
       D. Krishnamurthy and R. Murugavel*, 

       Ind. J. Chem., 2003, 42A, 2277-2282. 

65.  Reactivity Studies, Structural Characterization, and Thermolysis of Cubic Titanosiloxanes: Precursors to Titanosilicate Materials

       Which Catalyze Olefin Epoxidation 
       R. Murugavel*, P. Davis and V.S. Shete, 

       Inorg. Chem., 2003, 42, 4696-4706 DOI :10.1021/ic034317m

64.  Synthesis, characterization and structures of diphenyldiaminosilanes bearing bulky substituents on nitrogen 
       R. Murugavel*, N. Palanisami and R.J. Butcher, 

       J. Organomet. Chem., 2003, 675, 65-71 DOI :10.1016/S0022-328X(03)00233-X

63.  Synthesis, spectral characterization and crystal structures of organophosphonic diamides: pyramidal nitrogen centers and hydrogen

       bonding in [PhP(O)(NHtBu)2], [PhP(O)(NHDipp)2] (Dipp = 2,6-iPr2C6H3) and [tBuP(O)(NHiPr)2] 
       R. Murugavel* and R. Pothiraja, New. J. Chem., 2003, 27, 968-974 DOI :10.1039/b300035d

62.  First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)2(H2O)2]n assembly 
       R. Murugavel* and S. Banerjee, 

       Inorg. Chem. Commun., 2003, 6, 810-814 DOI :10.1016/S1387-7003(03)00112-6

-2002-

61.  Di-tert-butyl Phosphate as Synthon for Metal Phosphate Materials via Single-Source Coordination Polymers [M(dtbp)2]n (M = Mn,  

       Cu) and [Cd(dtbp)2(H2O)]n (dtbp-H = (tBuO)2P(O)OH 
       M. Sathiyendiran and R. Murugavel* Inorg. Chem., 2002, 41, 6404-6411 DOI :10.1021/ic0259787

60.  Anionic metal-organic and cationic organic layer alternation in the coordination polymers [{M(BTEC)(OH2)4]n.n(C4H12N2).4nH2O]n

       (M = Co, Ni, and Zn; BTEC = 1,2,4,5-benzenetetracarboxylate) 
       R. Murugavel*, D. Krishnamurthy and M. Sathiyendiran, J. Chem. Soc., Dalton Trans., 2002, 1, 34-39 DOI :10.1039/b105687p

-2001-

59.  Some recent developments in Titanium Alkoxide Chemistry 
       R. Murugavel* and P. Davis, 

       Titanium, 2001, 6, 16. 

58.  Reactions of 2-Mercaptobenzoic Acid with Divalent Alkaline Earth Metal Ions: Synthesis, Spectral Studies, and Single-Crystal x-ray

       Structures of Calcium, Strontium, and Barium Complexes of 2,2'-Dithiobis(benzoic acid) 
       R. Murugavel*, K. Baheti and G. Anantharaman, 

       Inorg. Chem., 2001, 40, 6870-6878 DOI :10.1021/ic010519b

57.  Metal containing new inorganic ring systems based on siloxane and phosphazane frameworks 
       R. Murugavel*, G. Prabusankar, V.S. Shete and K. Baheti, 

       Phosphorus, Sulfur, Silicon, 2001, 168-169, 263-268 DOI :10.1080/10426500108546565

56.  Synthesis and characterization of new (chloro)aminosilanes: X-ray crystal structure of [(2,6- Me2C6H3NH)2SiCl2] 

       M. G. Walawalkar and R. Murugavel* Phosphorus, Sulfur, Silicon, 2001, 174, 229-238 

55.  Synthesis of polyferromethylsiloxane sorbents using a sol-gel method 
       Y.L. Zub, H. W. Roesky*, M.M. Malyar, A.A. Chuiko, M. Jaroniec, R. Murugavel 

       Solid State Sciences, 2001, 3, 169-182 DOI :10.1016/S1293-2558(00)01124-9

54.  Synthesis and Structure of a Novel Lithium Gallosiloxane Containing a Ga4Si4O8 Macrocycle Analogous to the S8R Building Unit of

       Zeolites
       R. Murugavel*, M.G. Walawalkar, G. Prabusankar & P. Davis. Organometallics 2001, 20, 2639-2642. DOI: 10.1021/om0100636 

53.  A novel cyclic titanasiloxane derived from [Ph2Si(OH)]2O: synthesis and crystal structure of [Cp*Ti(Cl)(OSiPh2OSiPh2OSiPh2O)] 
       R. Murugavel*, V.S. Shete, K. Baheti, P. Davis, 

       J. Organomet. Chem., 2001, 625, 195-199 DOI :10.1016/S0022-328X(00)00946-3

52.  Is Water a Friend or Foe in Organometallic Chemistry? The Case of Group 13 Organometallic Compounds 
       H. W. Roesky*, M. G. Walawalkar andR. Murugavel 

       Acc. Chem. Res., 2001, 34, 201-211 DOI :10.1021/ar0001158

51.  Organic Soluble Silicophosphonate [RSi(OH){OP(O)(H)(OH)}]2O (R = (2,6-i-Pr2C6H3)NSiMe3): The First Silicophosphonate Containing

       Free Si-OH and P-OH Groups 
       R. Murugavel*, G. Prabusankar and M. G. Walawalkar 

       Inorg. Chem., 2001, 40, 1084-1085 DOI :10.1021/ic000960m

50.  Di-tert-butyl Phosphate Complexes of Cobalt(II) and Zinc(II) as Precursors for Ceramic M(PO3)2 and M2P2O7 Materials: Synthesis,  

       Spectral Characterization, Structural Studies, and Role of Auxiliary Ligands 
       R. Murugavel*, M. Sathiyendiran and M. G. Walawalkar 

       Inorg.Chem., 2001, 40, 427-434 DOI :10.1021/ic0006100

49.  Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials 
       R. Murugavel* and M. Sathiyendiran, 

       Chem.Lett., 2001, 1, 84-85. DOI :10.1246/cl.2001.84
 

-2000-

48.  Synthetic, spectroscopic, and structural studies on 4-aminobenzoate complexes of divalent alkaline earth metals: X-ray crystal

       structures of [{Mg(H2O)6}(4-aba)2].2H2O and [Ca(4-aba)2(H2O)2] 
       R. Murugavel*, V. V. Karambelkar and G. Anantharaman. Indian J. Chem., (Section A) 2000, 39, 843-850. 

47.  Coordination Polymers of Divalent Metal Ions Based on 1,2,4,5-Benzentetrapolycarboxylic Acid: Synthesis and Structure 
       D. Krishnamurthy, M. Sathiyendiran and R. Murugavel*, 

       Proc. Ind. Acad. Sci. (Chem. Sci.), 2000, 112, 395 

46.  Bulky Aryloxo Organotitanium Chlorides 
       G. Anantharaman, K. Baheti and R. Murugavel*, 

       Proc. Ind. Acad. Sci. (Chem. Sci.), 2000, 112, 373. 

45.  Extended metal-organic solids based on benzenepolycarboxylic and aminobenzoic acids 
       R. Murugavel*, G. Anantharaman, D. Krishnamurthy, M. Sathiyendiran and M. G. Walawalkar

       Proc.Ind. Acad. Sci. (Chem.Sci.), 2000, 112, 273-290 DOI :10.1007/BF02706178

44.  Synthesis, spectral characterization, and structural studies of 2-aminobenzoate complexes of divalent alkaline earth metal ions: x-

       ray crystal structures of [Ca(2-aba)2(OH2)3], [{Sr(2-aba)2(OH2)2}•H2O], and [Ba(2- aba)2(OH2)] (2-abaH = 2-NH2C6H4COOH) 
       R. Murugavel*, V.V. Karambelkar, G. Anantharaman and M. G. Walawalkar

       Inorg.Chem., 2000, 39, 1381-1390 DOI :10.1021/ic990895k
 

-1999-

43.  Synthesis and structure of a novel terminal imido complex of titanium 
       B.R. Jagirdar*, R. Murugavel and H. G. Schmidt 

       Inorg. Chim. Acta, 1999, 292, 105-107 DOI :10.1016/S0020-1693(99)00092-4

42.  Molecular titanosiloxanes as model compounds and precursors for titanosilicate materials 
       R. Murugavel*,

       In Advances In Metallo-organic Chemistry, 1999, pp.77-88 (Ed. R. Bohra), RBSA publishers. 

41.  Monovalent Group 13 organometallic compounds: weak association to monomeric, versatile two-electron donors 
       R. Murugavel* and V. Chandrasekhar* 

       Angew. Chem., 1999, 38, 1211-1215 DOI :10.1002/(SICI)1521-3773(19990503)38:9<1211::AID-ANIE1211>3.0.CO;2-O

40.  Molecular Phosphonate Cages: Model Compounds and Starting Materials for Phosphate Materials 
       M. G. Walawalkar, H. W. Roesky* and R. Murugavel. 

       Acc. Chem. Res., 1999, 32, 117-126 DOI :10.1021/AR980040W

39.  Conversion of Alkyltantalum Chlorides to Fluorides Using Trimethyltin Fluoride as a Fluorinating Agent. Crystal Structures of (p-

       MeC6H4CH2)3TaF2, (Me3SnCl•Me3SnF•TaF5)n, (Me3Si)2CHTaCl4,{(Me3Si)2CHTaCl4•[(Me3Si)2CH]2Ta2Cl6(m2-O)}, and (Me3Si)2CHTaF4 
       O.I. Guzyr, M. Schormann, J. Schimkowiak, H. W. Roesky*, C. Lehmann, M. G. Walawalkar, R. Murugavel, H. G. Schmidt and

       M. Noltemeyer, 

       Organometallics, 1999, 18, 832-836. DOI :10.1021/OM980768G

38.  Reactions of Trialkyl Phosphates with Trialkyls of Aluminum and Gallium: New Route to Alumino- and Gallophosphate Compounds

       via Dealkylsilylation 
       J. Pinkas, D. Chakraborty, Y. Yang, R. Murugavel, M. Noltemeyer and H. W. Roesky* Organometallics, 1999, 18, 523-528 

37.  Organosilanetriols: model compounds and potential precursors for metal-containing silicate assemblies 
       R. Murugavel, M. Bhattacharjee and H. W. Roesky* 

       Appl. Organomet. Chem., 1999, 13, 227-243
 

-1998-

36.  Gallophosphonates Containing Alkali Metal Ions. 2. Synthesis and Structure of Gallophosphonates Incorporating Na+ and K+ Ions 
       M. G. Walawalkar, R. Murugavel, H. W. Roesky*, I. Uson and R. Kraetzner, 

       Inorg. Chem., 1998, 37, 473-478 DOI :10.1021/IC971441V

35.  Silanetriols: preparation and their reactions 
       R. Murugavel, A. Voight, M. G. Walawalkar and H. W. Roesky* 

       Organosilicon Chemistry III: From Molecules to Materials, (Eds.: N. Auner and J. Weis), VCH, Weinheim, 1998. pp. 376-394

34.  Novel Organic-Soluble Molecular Titanophosphonates with Cage Structures Comparable to Titanium-Containing Silicates 
       M. G. Walawalkar, S. Horchler, S. Dietrich, D. Chakraborty, H. W. Roesky*, M. Schaefer, H. G. Schmidt, G.M. Sheldrick and

       R. Murugavel. 

       Organometallics, 1998, 17, 2865-2868 DOI :10.1021/OM971045K

33.  Synthesis and reactivity of cyclopentadienyl-free organolanthanides: reactions with group 13 complexes 
       S.A.A. Shah, R. Murugavel, H. W. Roesky* and H. G. Schmidt 

       Bull.Polish.Acad.Sci. Chem. 1998, 46, 157-166 
 

-1997-

32.  Organometallic Fluorides: Compounds Containing Carbon-Metal-Fluorine Fragments of d-Block Metals 
       E.F. Murphy, R. Murugavel and H. W. Roesky* 

       Chem.Rev.  1997, 97, 3425-3468 DOI :10.1021/CR960365V

31.   Syntheses, spectroscopy and crystal structures of new group 4 metallasiloxanes 
       A. Voight, R. Murugavel, H. W. Roesky* and H. G. Schmidt 

       J.Mol.Struct. 1997, 436-437, 49-57DOI :10.1016/S0022-2860(97)00222-6

30.  Organic-soluble neutral and ionic indium siloxane cages: potential precursors for indium-containing silicates 
       A. Voight, M. G. Walawalkar, R. Murugavel and H. W. Roesky*, E. Parisini and P. Lubini,

       Angew.Chem., 1997, 36, 2203-2205 DOI :10.1002/anie.199722031

29.  Soluble molecular titanosilicates 
       A. Voight, R. Murugavel, M.L. Montero, H. Wessel, F.Q. Liu, , H. W. Roesky*, I. Uson, T. Albers and E. Parisini, 

       Angew. Chem. 1997, 109, 1020-1022; Angew. Chem., Int. Ed. Engl.  1997, 36, 1001-1003 DOI :10.1002/anie.199710011

28.  Titanosilicates: recent developments in synthesis and use as oxidation catalysts 
       R. Murugavel and H. W. Roesky* 

       Angew. Chem., 1997, 109, 491-494; Angew. Chem., Int. Ed. Engl.,  1997, 36, 477-479. DOI :10.1002/anie.199704771

27.  The role of 2,4,6-tris(trifluoromethyl)phenylamino group in stabilizing new phosphorus-, arsenic-, and germanium-containing

       main-group compounds and transition-metal derivatives 
       J.T. Ahlemann, H. W. Roesky*, R. Murugavel, E. Parisini, M. Noltemeyer, H.G. Schmidt, O. Mü R, . Herbst-Irmer, L.N. Leonid ,

       G.Y. Shermolovich, 

       Chem. Ber., 1997, 130, 1113-1121. DOI :10.1002/cber.19971300813

26.  Syntheses, Spectroscopy, Structures, and Reactivity of Neutral Cubic Group 13 Molecular Phosphonates 
       M. G. Walawalkar, R. Murugavel, H. W. Roesky* and H. G. Schmidt 

       Inorg.Chem., 1997, 36, 4202-4207 DOI :10.1021/IC970346J

25.  A Novel Molecular Gallium Phosphonate Cage Containing Sandwiched Lithium Ions: Synthesis, Structure,and Reactivity 
       M. G. Walawalkar, R. Murugavel*, A. Voight, H. W. Roesky and H. G. Schmidt 

       J.Am.Chem.Soc., 1997, 119, 4656-4661 DOI :10.1021/JA964263Y

24.  Organometallic chemistry of C60 beyond λ2-C:C coordination: Buckminsterfullerenes as pentahapto (h5) cyclopentadienyl ligands 
       R. Murugavel* 

       Current Science 1997, 72, 231-232 

23.  The First Molecular Borophosphonate Cage: Synthesis, Spectroscopy, and Single-Crystal X-ray Structure 
       M. G. Walawalkar, R. Murugavel, H. W. Roesky* and H. G. Schmidt 

       Organometallics 1997, 16, 516-518 DOI :10.1021/OM960995N
 

-1996-

22. Stannasiloxanes with Acyclic, Bicyclic, and Cubic Core Structures: X-ray Crystal Structure of the Bicyclic Compound [RSi(OSnPh2O)3SiR]       (R = (2,6-Me2C6H3)NSiMe3) 
      A. Voight, R. Murugavel* and H. W. Roesky 

      Organometallics, 1996, 15, 5097-5101 DOI :10.1021/OM960522G

21.  Silanetriols: versatile precursors for new materials 
       M. G. Walawalkar, R. Murugavel and H. W. Roesky* Tailor-Made Silicon-Oxygen Compounds: From Molecules to Materials, 

20.  An efficient synthetic route to primary and secondary condensation products of silanetriols starting from

       (arylamino)trichlorosilanes 
       R. Murugavel, P. Boettcher, A. Voight, M. G. Walawalkar, H. W. Roesky*, E. Parisini, M. Teichert and M. Noltemeyer, J. Chem. Soc.,        

       Chem. Commun., 1996, 2417-2418. DOI :10.1039/cc9960002417

19.   Infrared and 29Si NMR spectroscopic investigations on metallosiloxanes derived from organosilanetriols 
       A. Voight, R. Murugavel*, U. Ritter and H. W. Roesky J.Organomet.Chem., 1996, 521, 279-286DOI :10.1016/0022-328X(96)06319-X

18.  Organometallic fluorides 
       M. G. Walawalkar, R. Murugavel and H. W. Roesky* 

       Eur.J.Solid State Inorg.Chem., 1996, 33, 943-955

17.   Hetero- and Metallasiloxanes Derived from Silanediols, Disilanols, Silanetriols, and Trisilanols 
       R. Murugavel, A. Voight, M. G. Walawalkar and H. W. Roesky* 

       Chem.Rev., 1996, 96, 2205-2236DOI :10.1021/CR9500747

16.  Cubic Group 13 Heterosiloxanes with Four Co3(CO)9 Cluster Units as Substituents: Novel Soluble Model Compounds for Synthetic

       Zeolites Showing Catalytic Activity in Hydroformylation Reactions 
       U. Ritter, N. Winkhofer, R. Murugavel, A. Voight, D. Stalke and H. W. Roesky* 

       J.Am.Chem.Soc., 1996, 118, 8580-8587 DOI :10.1021/JA952986W

15.   Silanediols derived from silanetriols. X-ray crystal structures of (2,4,6-Me3C6H2)N(SiMe3)Si(OSiMe3)(OH)2 and (2,4,6-

       Me3C6H2)N(SiMe3)Si(OSiMe2R)(OH)2 [R = CH2(2-NH2-3,5-Me2C6H2)] 
       R. Murugavel, A. Voight, V. Chandrasekhar, H. W. Roesky*,H. G. Schmidt and M. Noltemeyer, 

       Chem.Ber., 1996, 129, 391-5 DOI :10.1002/cber.19961290405

14.   Synthesis and structure of gallium siloxane cages: model substances for gallium-containing silicates 
       A. Voight, R. Murugavel*, E. Parisini and H. W. Roesky 

       Angew.Chem., Int.Ed.Engl., 1996, 35, 748-50 DOI :10.1002/anie.199607481

13.   Discrete Silanetriols: Building Blocks for Three-Dimensional Metallasiloxanes 
       R. Murugavel, V. Chandrasekhar and H. W. Roesky* 

       Acc.Chem.Res. , 1996, 29, 183-9 DOI :10.1021/AR950154X

12.   Facile and Rational Route for High-Yield Synthesis of Titanasiloxanes from Aminosilanetriols 
       A. Voight, R. Murugavel, V. Chandrasekhar, N. Winkhofer, H. W. Roesky*, H. G. Schmidt and I. Uson, 

       Organometallics, 1996, 15, 1610-13 DOI :10.1021/OM950816M

11.   Synthesis, spectroscopic and structural characterization of the first mixed fluoro-bromo Group 4 organometallic complex

       [{Cp*ZrF2Br}4] (Cp* = C5Me5) 
       E.F. Murphy, R. Murugavel, H. W. Roesky*, M. Noltemeyer and H. G. Schmidt 

       Z.Anorg.Allg.Chem., 1996, 622, 579-82 

10.  Cyclic and Polyhedral Aluminosiloxanes with Al2Si2O4, Al4Si2O6, and Al4Si4O12Frameworks: X-rayCrystal Structures of [(2,4,6-

       Me3C6H2)N(SiMe3)Si(OAlBu-i)(OAl(Bu-i)2)O]2 and [(2,6-Me2C6H3)N(SiMe3)SiO3Al•C4H8O2]4 
       V. Chandrasekhar, R. Murugavel*, A. Voight, H. W. Roesky, H. G. Schmidt and M. Noltemeyer, 

       Organometallics, 1996, 15, 918-22 DOI :10.1021/OM950685P
 

-1995-

9.    New Lipophilic Air-Stable Silanetriols: First Example of an X-ray Crystal Structure of a Silanetriol with Si-N Bonds 
       R. Murugavel, V. Chandrasekhar, A. Voight, H. W. Roesky*, H. G. Schmidt, M. Noltemeyer, 

       Organometallics, 1995, 14, 5298-301 DOI :10.1021/om00011a054

8.    Preparation, spectral characterization, and single crystal x-ray structures of cis and trans isomers of 2,4,6- trifluoroethoxy-1,3,5-

       triethyl-1,3,5,2λ3, 4λ5, 6λ5-triazatriphosphorinane-2,4,6-trioxide, [EtNP(O)(OCH2CF3)]3 
       R. Murugavel*, N. Thirupathi, S.S. Krishnamurthy and M. Nethaji, 

       Heteroatom Chem., 1995, 6, 63-70 DOI :10.1002/hc.520060114

7.    Synthetic, Spectroscopic and Structural Investigations on Cyclic and Acyclic Phosphazanes and their Transition Metal Complexes 
       R. Murugavel. 

       J. Indian. Inst. of Science, 1995, 229-231 
 

-1994-

6.    New insights into the chemistry of cyclic phosphorus-nitrogen compounds 
       S. Narasimhamurthy, N. Thirupathi, R. Murugavel and S.S. Krishnamurthy*, 

       Phosphorus, Sulfur, Silicon, 1994, 93-94(1-4), 221-6 DOI :10.1080/10426509408021821

5.    Reactions of the hexachlorocyclodiphosphazane [MeNPCl3]2 with primary aromatic amines: formation of highly basic

       bisphosphinimines 
       R. Murugavel, S.S. Kumaravel, S.S. Krishnamurthy*, M. Nethaji and J. Chandrasekhar, , 

       J. Chem. Soc., Dalton Trans., 1994, 847-852. DOI :10.1039/DT9940000847
 

-1993-

4.    When does a nitrogen attached to a λ3-phosphorus assume a pyramidal geometry? Crystal structures of Group 6 metal carbonyl

       complexes of isomeric forms of λ3-cyclotriphosphazanes 
       R. Murugavel, S.S. Krishnamurthy* and M. Nethaji, J. Chem. Soc., Dalton Trans., 1993, 3635-3639. DOI :10.1039/DT9930003635

3.    Synthesis, spectral characterization and single-crystal structure of a bicyclic tetraphosphapentazane tetraoxide,

       N5P4Et5O4(OC6H3Me2-2,6)2 
       R. Murugavel, S.S. Krishnamurthy* and M. Nethaji, J.Chem.Soc., Dalton Trans., 1993, 2569-73.DOI :10.1039/DT9930002569

2.    Organometallic chemistry of diphosphazanes. Part 7. Platinum(II), palladium-(0), -(I) and -(II) complexes of RN[P(OPh)2]2 (R = Me or        Ph) 
       M.S. Balakrishna, S.S. Krishnamurthy*, R. Murugavel, M. Nethaji and I.I. Mathews, 

       J.Chem.Soc., Dalton Trans.,  1993, 477-82. DOI :10.1039/DT9930000477

1.     Syntheses, spectroscopy, structures, and conformations of l3-cyclotriphosphazanes: role of negative hyperconjugation 
       R. Murugavel, S.S. Krishnamurthy*, J. Chandrasekhar and M. Nethaji, 

       Inorg.Chem.,1993, 32, 5447-53 DOI :10.1021/ic00076a008