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223. Ligand-Field Directed Electronic Effects in Heterogenized Bifunctional Co (II) Molecular Clusters Accomplish Efficient Overall Water            Splitting

        A. Borah, J. Saha, S. Sharma, S. Chaudhary, S. K. Gupta, G. Rajaraman, C. Subramaniam, R.Murugavel

       ACS Catal. 2023, 13, 13, 8535–8550

222. Futuristic storage devices: Single molecular magnets of rare earths versus spin crossover systems of earth-abundant metals

        G. BhattA. Ghatak, R.Murugavel

        J Chem Sci 2023, 135, 40 

221. Controlling metal coordination geometry in dinuclear zinc and cadmium hydroxy aryl carboxylates incorporating five-membered              aromatic cyclic amine co-ligands

        P. Pandey, G. Manibalan,  R.Murugavel

        Inorganica Chimica Acta 2023, 551, 121461

220. Electron Paramagnetic Resonance Spectra of Pentagonal Bipyramidal Gadolinium Complexes

        J. B. Petersen, Y. Ding, S. Gupta​, A. Borah, E. J. L. McInnes, Y. Z. Zheng, R. Murugavel, R. E. P. Winpenny

       Inorg. Chem. 2023, 62, 21, 8435–8441


219. Nuclearity Control in Molecular Copper Phosphates Derived from a Bulky Arylphosphate: Synthesis, Structural and Magnetic Studies

       T. PrapakaranC. I. Sathish J. YiA. VinuR. Murugavel

       Eur. J. Inorg. Chem. 2023, 26, e202300071

218. Field-induced SIM behaviour in early lanthanide(III) organophosphates containing 18-crown-6

      A. Borah , S. Dey , S. K. Gupta , G. Rajaraman  and R. Murugavel

       Dalton Trans., 2023, 52, 8943-8955

217. A rigid calcium 2-ethylhexylphosphate one-dimensional polymer: synthesis, structure, thermal behaviour and decomposition                   chemistry

      N. Matharoo , M. G. Walawalkar  and R. Murugavel

       Dalton Trans., 2023, 52, 2412-2423


216. 4, 4′-Methylenebis [N-(2-hydroxy-3-methoxybenzylidene)-2, 6-diisopropylaniline]

        T. Prapakaran, R. Murugavel

         IUCrDATA,2022,7, 2414-3146

215. Alkali Metal Di-tert-butyl Phosphates: Single-Source Precursors for Homo- and Heterometallic Inorganic Phosphate Materials

        S. Verma and R. Murugavel

        Inorg. Chem. 2022, 61, 18, 6807–6818

214. Supramolecular aggregation in sterically encumbered monoarylphosphates and their H-bonded adducts: multigram synthesis of       

        elusive 2, 6-di-tert-butylphenyl phosphate

        T. Prapakaran, S. Kuppuswamy, R. Murugavel

         CrystEngComm, 2022, 24, 3481-3491 


213. Magnetic relaxation in single-ion magnets formed by less-studied lanthanide ions Ce(III), Nd(III), Gd(III), Ho(III), Tm(II/III) and                  Yb(III)

        A. Borah, R. Murugavel

        Coordination Chemistry Reviews, 2021,214288

212. Deciphering the role of anions and secondary coordination sphere in tuning anisotropy in Dy(III) air-stable D5h SIMs

        R. MurugavelS. K. GuptaS. DeyT. RajeshkumarG. Rajaraman

        Chem. Eur. J. 10.1002/chem.202103585

211. The Redox Journey of Iconic Ferrocene: Ferrocenium Dications and Ferrocenate Anions

        M. G. WalawalkarP. Pandey, R. Murugavel

        Angew. Chem. Int. Ed., 2021, 60, 12632–12635.

210. Multifunctionality-assisted supramolecular architecture formation in tert-butyl phosphonic acid adducts with cytosine and                       adenine

      S. Shanmugan, T. Prapakaran, M. G. Walawalkar, R. Murugavel 

        Emergent Materials, 2021, 4, 597–60


209. Facile synthesis of NiO@Ni(OH)2-α-MoO3nanocomposite for enhanced solid-state symmetric supercapacitor application

        G. Manibalan, Y. Govindaraj, J. Yesuraj, P. Kuppusami, G. Murugavdoss, R. Murugavel, M. R. Kumar  

       Journal of Colloid and Interface Science,2021,585, 505-518

208. Cyclopentadienyl Removal Assisted Nuclearity Expansion in Thermolabile Titanium and Zirconium Organophosphates Sourced from         Metallocene Dichlorides

        S. Verma, G. A Bhat and R. Murugavel

        J. Organomet. Chem, 2021, 932, 121642

207. Dinuclear Group 12 Metal Phosphates Bridged by Hexadentate 2,3,5,6-Tetra(2-pyridyl)-pyrazine and their Supramolecular                             Organization

        G. A Bhat and R. Murugavel 

        J. Mol. Struct, 2021, 1224, 128960



206. Enhancing the barrier height for Yb(iii) single-ion magnets by modulating axial ligand fields

        A. BorahS. DeyS. K. Gupta, M. G. WalawalkarG. Rajaraman and  R. Murugavel   

       Chem. Commun., 2020,56, 11879-11882

205. Cyclic zinc organophosphate based expanded ditopic N,N′-metalloligands

        G. A Bhat and R. Murugavel 

       J Chem Sci. 2020, 132, 121 

204. Di-tert-butylphosphate Derived Thermolabile Calcium Organophosphates: Precursors for Ca(H2PO4)2, Ca(HPO4), α-/β-Ca(PO3)2, and           Nanocrystalline Ca10(PO4)6(OH)2

        S. Verma and R. Murugavel

        Inorg. Chem. 2020, 59, 18, 13233–13244

203. Nanoporous Covalent Organic Framework Embedded with Fe/Fe3O4 Nanoparticles as Air-Stable Low-Density Nanomagnets

        R. Kushwaha, D. Kaleeswaran, S. Haldar, D. Chakraborty, D. Mullangi, A. Borah, C. P. Vinod, R. Murugavel, and R. Vaidhyanathan

        ACS Appl. Nano Mater. 2020, 3, 9, 9088–9096

202. Discrete and Polymeric Cobalt Pyrophosphates Derived from Pyrophosphoric Acid Diester Ar2H2P2O7

       K.Sharma, S. K. Gupta and R Murugavel

         Eur. J. Inorg. Chem., 2020: 2352-2361

201. Compositional Control as the Key for Achieving Highly Efficient OER Electrocatalysis with Cobalt Phosphates Decorated Nanocarbon           Florets

      J.Saha, S. Verma, R. Ball, C. Subramaniam and R. Murugavel

       Small 2020, 16, 1903334


200. Easily Accessible Layered Alkali Metal Organophosphates: Synthesis, Structure and Water Assisted Proton Conductivity

        S. K. Gupta, D. Dutta, S. Kuppuswamy, A. J. Bhattacharyya and R. Murugavel

        Chem.-Euro. J. 2019, under revision.

199. Editorial: Special issue on 150 years of the periodic table

        E. D. Jemmis, J. N. Moorthy, and R. Murugavel

        J. Chem. Sci. 2019, 131: 113.

198. High-pressure crystallographic and magnetic studies of pseudo-D5h symmetric Dy(III) and Ho(III) Single Molecule Magnets

        M. Norre, C. Gao, S. Day, S. Gupta, A. Borah, R. Murugavel, G. Rajaraman, and J. Overgaard

        Inorg. Chem. 2019, 58, 0000-0000.

197. An Unprecedented Structural and Functional Mimic for Copper Amine Oxidase

        R. Jangir, M. Ansari, D. Kaleeswaran, G. Rajaraman, M. Palaniandavar, and R. Murugavel

        ACS Catalysis, 2019, 9, 10940-10950.

196. Ceramic and Framework Phosphates Derived from Mono and Diesters of Phosphoric Acid

        R. Murugavel

        Emergent Materials, 2019, 2, 273-294.

195. Facile Exfoliation of Single-Crystalline Copper Alkylphosphate van der Waals Solids to SingleLayer Nanosheets and Enhanced         


       G. A. Bhat, S. Halder, D. Chakraborty, S. Verma, R. Vaidhyanathan and R. Murugavel

       Angew. Chem. Int. Ed., 2019, 58, 16844–16849.


194. Compositional Control as the key for achieving highly efficient OER electrocatalysis with cobalt phosphates decorated nanocarbon              florets

        J. Saha, S. Verma, R. Ball, C. Subramaniam, and R. Murugavel

        Small, 2019, 1903334.

193. A Single-electron Single-ion Cerous Magnet

        Sandeep K. Gupta, S. Shanmugan, T. Rajeshkumar, G. Rajaraman and R. Murugavel

        Dalton. Trans. 2019, 48, 15928-15935.

192. Hitherto unknown eight-connected frameworks formed from A4B4O12 metal organophosphate heterocubanes

        K. Sharma, S. K. Gupta and R. Murugavel

        Chem. Commun. 2019, 55, 7994-7997.

191. Bimetallic nanoparticles anchored on core-shell support as an easily recoverable and reusable catalytic system for efficient                         nitroarene reduction     

       R. Antony, R. Marimuthu, and R. Murugavel

       ACS Omega, 2019, 4, 9241-9250.

190. A Compelling and Complete Account of p-Block Chemistry, A review of the book “The Chemistry of the p-Block Elements: Syntheses,          Reactions and Applications”

        Anil J. Elias. R. Murugavel

        Resonance, 2019, 24, 115-116.

189. Effect of benzoic acid substituents and additional functional groups of ancillary ligands in modulating the nuclearity and                             aggregation behavior of transition metal carboxylates

       P. Rajakannu, D. Kaleeswaran, S. Banerjee, R. J. Butcher, R. Murugavel

       Inorg. Chim. Acta, 2019, 486, 283-293.




188. A decade of “Chemical Frontiers Goa” 

        R. Murugavel and C. N. R. Rao

        RSC Adv., 2018, 8, 28602-28603.  


187.  2,2′,6,6′‐Tetraisopropylbenzidine‐Based Sterically Encumbered Ditopic C2‐Symmetric Ligand Systems and Supramolecular Building


        R. Jangir, D. Kaleeswaran,  R. Murugavel

        ChemistrySelect, 2018, 3, 8082-8094.


186. Thermolabile Organotitanium Monoalkyl Phosphates: Synthesis, Structures, and Utility as Epoxidation Catalysts and Single-Source

        Precursors for TiP2O7

        G. A. Bhat, S. Verma, R. Antony, R. Murugavel

        Inorg. Chem., 2018, 57, 7644-7654.


185.  Polydentate 4‐Pyridyl‐terpyridine Containing Discrete Cobalt Phosphonate and Polymeric Cobalt Phosphate as Catalysts for Alcohol   


        G. A. Bhat, R. Antony, R. Murugavel

        Z. Anorg. Allg. Chem., 2018, xx, xxx-xxx.


184. Bulky 2,6-dibenzhydryl-4-methylphenyl β-diiminato derived complexes of Pd(II) and Cu(II): Efficient catalysts for Suzuki coupling

       and alcohol oxidation

       P. Saxena, R. Murugavel

       J. Organomet. Chem., 2018, 868, 76-85.


183. 1,3,5-Triphenylbenzene: a versatile photoluminescent chemo-sensor platform and supramolecular building block (Review Article)

       P. Vishnoi, D. Kaleeswaran, R. Murugavel

       RSC. Adv., 2018, 8, 17535-17550.


182. A [4+2] Condensation Strategy to Imine‐Linked Single‐Crystalline Zeolite‐Like Zinc Phosphate Frameworks

       R. Janghir, A. Ch. Kalita, D. Kaleeswaran, S. K. Gupta, R. Murugavel

       Chem. Eur. J., 2018, 24, 6178-6190.


181. Enriching lanthanide single-ion magnetism through symmetry and axiality (Feature Article)

       S. K. Gupta, R. Murugavel

       Chem. Commun., 2018, 54, 3685-3696.


180. Synthesis, characterisation, nuclease and cytotoxic activity of phosphate-free and phosphate-containing copper 4′4′-(N-

        methylpyridinium)-2,2′:6′,2′′2,2′:6′,2′′ terpyridine complexes

       Gulzar A. Bhat, R. Murugavel

       J. Chem. Sci., 2018, 130(2), 1-12.


179. Dinuclear Mn(II), Co(II) and Ni(II) Arylphosphates Incorporating 4ʹ-Chloro-2,2ʹ:6ʹ,2ʹʹ-Terpyridine Co-ligand: Efficient Catalysts for

       Alcohol Oxidation

       Gulzar A. Bhat, R. Antony, R. Murugavel

       Eur. J. Inorg. Chem., 2018, 795-804.


178. Picric acid sensing and CO2 capture by a sterically encumbered azo-linked fluorescent triphenylbenzene based covalent

       organic polymer

       D. Kaleeswaran, R. Murugavel

       J. Chem. Sci., 2018, 130 (1), 1-14.


177. Is strong axial crystal-field the only essential condition for large magnetic anisotropy barrier? Case of non-Kramers Ho(III) versus     


       S. K. Gupta, T. Rajeshkumar, G. Rajaraman, R. Murugavel

       Dalton. Trans., 2018, 47, 357-366.


176. Delineating factors that dictate the framework of a bulky phosphate derived metal complexes: Sterics of phosphate, anion of the

       metal salt and auxiliary N-donor ligand

       P. Saxena, S. K. Mandal, K. Sharma. R. Murugavel

       Inorg. Chim. Acta, 2018, 469, 353-365.


175. Ethoxysilane appended M(II) complexes and their SiO2/MCM-41 supported forms as catalysts for efficient oxidation of secondary


       R. Antony, R. Marimuthu, P. Vishnoi, R. Murugavel

       Inorg. Chim. Acta, 2018, 469, 173-182.



174. Rare Supramolecular Assemblies of a Dicopper(II)-tetracarboxylate Stabilized by (Methanol)6, Dimethyl Sulfoxide and 4,4′-

       Azobipyridyl Bridges

       P. Vishnoi, D. Kaleeswaran, R. Murugavel

       ChemistrySelect, 2017, 2, 12014-12018.


173. [Am]Mn(H2POO)3: A New Family of Hybrid Perovskites Based on the Hypophosphite Ligand

       Y. WuS. ShakerF. Brivio, R. MurugavelP. D. Bristowe, A. K. Cheetham* 

       J. Am. Chem. Soc., 2017, 139, 16999.


172. Complex Structural Landscape of Titanium Organophosphonates: Isolation of Structurally Related Ti4, Ti5, and Ti6 Species and 

       Mechanistic Insights

       Kamna Sharma, R. Antony, Alok. Ch. Kalita, Sandeep K. Gupta, Paul Davis, R. Murugavel

       Inorg. Chem., 2017, 56, 12848-12858.


171. Bulky 2,6-Dibenzhydryl-4-methylaniline Derived Schiff Base Complexes of Pd(II) as Efficient Catalysts for Suzuki Coupling: Effect of

       Coordinated Anion on the Catalytic Activity

       Priya Saxena, R. Murugavel

       ChemistrySelect, 2017, 2, 9577-9585.


170. Selective formation of discrete versuspolymeric copper organophosphates: DNA cleavage and cytotoxic activity

       Gulzar A. Bhat, R. Maqbool, Aijaz. A. Dar, M.U. Hussain, R. Murugavel

       Dalton Trans., 2017, 46, 13409-13420.


169. Catalysis and CO₂ capture by palladium incorporated covalent organic frameworks

       D. Kaleeswaran, R. Antony, A. Sharma, A. Malani, R. Murugavel

       ChemPlusChem, 2017, 82, 1253-1265.


168. Intriguing structural chemistry of neutral and anionic layered monoalkylphosphates: single-source precursors for high-yield    

       ceramic phosphatesolymer

       G. A. Bhat, A. Ch. Kalita, R. Murugavel

       CrystEngComm, 2017, 19, 5390-5401.


167. Lanthanide Organophosphate Spiro Polymers: Synthesis, Structure, and Magnetocaloric Effect in the Gadolinium Polymer

       S. K. Gupta, G. A. Bhat, R. Murugavel

       Inorg. Chem., 2017, 56, 9071-9083.


166. Sterically encumbered 2,6-dibenzhydryl-4-methylphenyl derived ligand systems: synthesis and structures

       P. Saxena, R. Murugavel

       J. Chem. Sci., 2017, 129, 1499-1512.


165. Bulky Isopropyl Group Loaded Tetraaryl Pyrene Based Azo-Linked Covalent Organic Polymer for Nitroaromatics Sensing and CO2


       S.K. Gupta, D. Kaleeswaran, S. Nandi, R. Vaidhyanathan, R. Murugavel

       ACS Omega 2017, 2 , 3572-3582.


164. Bulky 2, 6‐Dibenzhydryl‐4‐methylaniline Derived Schiff Base Complexes of Pd(II), Cu(II)   and Co (II) as Efficient Catalysts for Suzuki

       Coupling and Alcohol Oxidation Reactions

       P. Saxena, R. Murugavel

       ChemistrySelect 2017, 2, 3812 – 3822.   


163. Pentanuclear Lanthanide Mono-organophosphates: Synthesis, Structure, and Magnetism

        S.K. Gupta, S.K. Langley, Kamna Sharma, K.S. Murray, and R. Murugavel

        Inorg. Chem., 20107, 56, 3946-3960. 


162. Triphenylbenzene Sensor for Selective Detection of Picric Acid

       S. Nagendran, P. Vishnoi, and R. Murugavel

       J. Floures., 2017, 27, 1299–1305.


161. Five different pseudo-polymorphs of 4-aminoarylphosphate: Supramolecular  aggregation in  organophosphates

       Kamna Sharma, Alok Ch. Kalita and R. Murugavel

       CrystEngComm, 2017, 19, 1058–1070.


160. Elusive Double-Eight-Ring Secondary Building Unit

       S. K. Gupta, A. Ch. Kalita, A. A. Dar, S. Sen, G. N. Patwari and R. Murugavel

       J. Am. Chem. Soc. 2017, 139, 59-62.



159. Zinc Dialkylhydroxybenzoates with Unusual Structures: First Example of a Discrete Three-Blade Paddle-Wheel and a Solvent    

       Engulfed Coordination Polymer

       P. Vishnoi, S. K. Sharma, D. Kaleeswaran and R. Murugavel

       ChemistrySelect, 2016, 1, 6658–6668.


158. Alkyl-Chain-Separated Triphenybenzene - Carbazole Conjugates and their Derived Polymers:  Candidates for Sensory, Electrical and  

       Optical Materials

       D. Kaleeswaran, P. Vishnoi, S. Kumar, S. Chithiravel, M. G. Walawalkar, K. Krishnamoorthy and R. Murugavel

       ChemistrySelect, 2016, 1, 6649–6657.


157. Dependence of the SBU length on the size of metal ions in alkaline earth MOFs derived from a   flexible C3-symmetric tricarboxylic


       P. Vishnoi, D. Kaleeswaran, A. Ch. Kalita and R. Murugavel

       CrystEngComm, 2016, 18, 9130–9138.


156. Unprecedented Zero Field Neodymium(III) Single-Ion Magnet Based on a Phosphonic Diamide

       S. K. Gupta, T. Rajeshkumar, G. Rajaraman and R. Murugavel

       Chem. Commun.  2016, 52, 7168-7171.


155. Dimensionality Alteration and Intra- versus Inter-SBU Void Encapsulation in Zinc Phosphate Frameworks

       A. A. Dar, G. A. Bhat, and R. Murugavel

       Inorg. Chem. 2016, 55, 5180-5190.


154. An Air-Stable Dy(III) Single-Ion Magnet with High Anisotropy Barrier and Blocking Temperature

       S. K. Gupta, T. Rajeshkumar, G. Rajaraman, and R. Murugavel

       Chem. Sci. 2016, 7, 5181-5191.


153. A Solvent Switch for Stabilization of Multiple Hemiacetals on an Inorganic Platform: Role of Supramolecular Interactions

       A. Ch. Kalita, S. K. Gupta, R. Murugavel

       Chem. Euro. J. 2016, 22, 6863-6875.


152. Three-Fold C3-Symmetric Off-On Fluorescent Chemo-Sensors for Fluoride Ions

       P. Vishnoi, S. Sen, G. N. Patwari, and R. Murugavel

       J. Fluorescence 2016, 26, 997–1005.


151. New Sterically Encumbered Arylimido Hexamolybdates for Organic Oxidation Reactions,

       R. Jangir, R. Antony and R. Murugavel

       New J. Chem., 2016, 40, 1004-1013.



150. Octanuclear Zinc Phosphates with Hitherto Unknown Cluster Architectures: Ancillary Ligand and   Solvent Assisted Structural

        Transformations Thereof

       A.A. Dar, S. Sen, S.K. Gupta, G.N. Patwari and R. Murugavel

       Inorg. Chem., 2015,54, 9458-9469.  


149. Anhydrous manganese hypophosphite dense framework solid: Synthesis, structure and magnetic studies

       G.A. Bhat, P. Vishnoi, S.K. Gupta and R. Murugavel

       Inorg. Chem. Commun., 2015, 59, 84-87.


148. [3+ 3] Imine and β-ketoenamine tethered fluorescent covalent-organic frameworks for CO2 uptake and nitroaromatic sensing

       D. Kaleeswaran, P. Vishnoi and R Murugavel

       J. Mater. Chem. C, 2015, 3, 7159-7171.


147. Is single-4-ring the most basic but elusive secondary building unit that transforms to larger structures in zinc phosphate chemistry? 

       A.A. Dar, S.K. Sharma and R. Murugavel

       Inorg. Chem., 2015, 54, 4882-4894. 


146. 2, 6-Dimethylphenol derived H-phosphonate and α-hydroxyphosphonate: facile synthesis, crystal chemistry, supramolecular

       association and metal complexation
S. Hossain, S.K. Gupta and R Murugavel

       Cryst. Eng. Comm., 2015, 17, 4355-4366.

145. Discrete {Gd III 4 M}(M= Gd III or Co II) pentanuclear complexes: a new class of metal-organophosphate molecular coolers
S.K. Gupta, A.A. Dar, T. Rajeshkumar, S. Kuppuswamy, S.K. Langley, K.S. Murray, G. Rajaraman and R. Murugavel

       Dalton Trans., 2015, 44, 5961-5965

144. Discrete and polymeric cobalt organophosphates: isolation of a 3-D cobalt phosphate framework exhibiting selective CO2 capture

       S.K. Gupta, S. Kuppuswamy, J.P.S. Walsh, E.J.L. McInnes and R. Murugavel

       Dalton Trans., 2015, 44, 5587-5601.

143. Synthetic strategies to achieve further-functionalised monoaryl phosphate primary building units: crystal structures and solid-state

       aggregation behavior

       A.A. Dar, A. Mallick and R. Murugavel

       New J. Chem., 2015, 39, 1186-1195.

142. Role of 4, 4'-bipyridine versus longer spacers 4, 4'-azobipyridine, 1, 2-bis (4-pyridyl) ethylene,  and 1, 2-bis (pyridin-3-ylmethylene)    

       hydrazine in the formation of thermally labile metallophosphate coordination polymers

       P. Rajakannu, R. Howlader, A.C. Kalita, R.J. Butcher and R. Murugavel

       Inorg. Chem. Front., 2015, 2, 55-66.



141. Containment of Polynitroaromatic Compounds in a Hydrogen Bonded Triarylbenzene Host
 P. Vishnoi, M. G. Walawalkar and R. Murugavel* 

       Crystal Growth Des. 2014, 14, 5668-5673. (Special Issue on the Int. Year of Crystallography 2014).

140. Charge Transfer Aided Selective Sensing and Capture of Picric Acid by Triphenylbenzenes
P. Vishnoi, S. Sen, G. N. Patwari* and R. Murugavel* 

       New J. Chem. 2014, 39, 886-892.

139. Isolation and characterization of nanosheets containing few layers of the Aurivillius family of oxides and metal-organic compounds.
M. B. Sreedhara; B.E. Prasad, M. Moirangthem,; R. Murugavel, C.N.R. Rao

       J. Solid State Chem., 2014 , 224, 21-27. (Special Issue on 2D Materials).


138. An anionic two-dimensional indium carboxylate framework derived from a pseudo C3 -symmetric semi-flexible tricarboxylic acid.
P. Vishnoi; A.C. Kalita; R. Murugavel

       J. Chem. Sci., 126, 1385-1391.

137. Auxiliary ligand aided tuning of aggregation in transition metal benzoates: Isolation of four different types of coordination polymers.
S. Banerjee, R. Palanisamy, R. Murugavel and  R.J. Butcher

       CrystEngComm., 2014, 16, 8429-8441.

136. Ab Initio Chemical Synthesis of Designer Metal Phosphate Frame- Works at Ambient Conditions.
A. Kalita, N. Gogoi, R. Jangir, S. Kuppuswamy, M. G. Walawalkar, R. Murugavel*

       Inorg. Chem., 2014, 53, 8959-8969.


135. A Flexible Tri-carboxylic Acid Derived Zinc(II) 3D Helical Metal-Organic-Framework and a Cadmium(II) Interwoven 2D Layered

       Framework Solid.
P. Vishnoi, R. Murugavel*

       Z. Anorg. Allg. Chem., 2014, 640, 1075-1080. (Prof. CNR Rao's 80th birthday Festschrift).

134. Selective fluorescence sensing of polynitroaromatic explosives using triaminophenylbenzene scaffolds.
P. Vishnoi, M. G. Walawalkar; S. Sen, A. Datta, G.N. Patwari and R. Murugavel* 

       Phys.Chem.Chem.Phys., 2014, 16, 10651-10658.

133. Fluoride Ion Sensing and Caging by a Preformed Molecular D4R Zinc Phosphate Heterocubane.
A. Kalita, R. Murugavel

       Inorg. Chem., 2014, 53, 3345-3353.

132. Polymeric and cyclic manganese phosphates and phosphinates: Synthesis, spectral characterization and solid-state structures.
R. Pothiraja, R. Palanisamy, P. Vishnoi, R.J. Butcher and R. Murugavel*

       Inog. Chim. Acta, 2014, 414 264-273.

131. Organotitanium phosphates with free P-OH groups: Synthesis, spectroscopy and solid state structures.
L. Kalita, A. Kalita and R. Murugavel* 

       J. Organomet. Chem., 2014, 751, 555-562. (Special Issue on the 50 Years of JOMC)

130. Pseudopolymorphism leading and two different supramolecular aggregations in a phosphate monoester: role of a rare water-dimer.
A. Kalita, K. Sharma and R. Murugavel*

       Cryst. Eng. Comm., 2014, 16, 51-55.



129. Mono and dinuclear group 12 phosphonates derived from a sterically encumbered phosphonic acid: Observation of esterification
R. Howlader, M. G. Walawalkar and R. Murugavel

       Inorganica Chimica Acta, 2013, 405, 147-154.


128. Non-covalently aggregated zinc and cadmium complexes derived from substituted aromatic carboxylic acids: Synthesis,  

       spectroscopy, and structural studies
N. Palanisami, R. Palanisamy and R. Murugavel

       Inorganica Chimica Acta, 2013, 405, 522-531.

127. Cationic D4R zinc phosphate-anionic polyoxometalate hybrids: synthesis, spectra, structure and catalytic studies
A. Kalita, C. Roch-Marchal and R. Murugavel

       Dalton Trans., 2013, 42, 9755-9763.



126. Secondary Building Units and Framework Structures in Aluminium and Zinc Phosphates: The Connection Between
R. Murugavel* and C.N.R. Rao*

       In Book Chapter - Metal Phosphonate Chemistry: From Synthesis to Applications

       Royal Society of Chemistry, 2012, 344-363.


125. Cyclopentadiene Based Low-Valent Group 13 Metal Compounds: Ligands in Coordination Chemistry and Link between Metal Rich

       Molecules and Intermetallic  Materials
S. Gonzáz-Gallardo, BT. ollermann, R.A. Fischer* and R. Murugavel* 

       Chem. Rev., 2012, 112, 3136-3170.

124. Synthesis and Molecular Structures of Carboxylic Acid Group Bearing Two Ketoimines that Exist in Enaminone Form 
R. Murugavel*, M. P. Singh, and M. Nethaji

       J. Chem. Cryst., 2012, 42, 12-17.



123. Synthesis and structural characterization of dinuclear complexes of trivalent aluminum, gallium, indium and chromium derived    

       from pyrazole-2-ethanol
L. Kalita, M. G. Walawalkar and R. Murugavel* 

       Inorganica Chimica Acta, 2011, 377, 105-110

122. Reactions of [(Me3Si)3CAlMe2] with substituted benzoic acids. Isolation of a rare organoalumoxane carboxylate 
L. Kalita, R. Pothiraja, V. Saraf, M. G. Walawalkar, R.J. Butcher and R. Murugavel*

       J. Organomet. Chem., 2011, 696, 3155-3161.

121. Supramolecular aggregation in alkaline earth metal 3- and 4-hydroxybenzoates using 1,10-phenanthroline auxiliary. 
R. Korah, L. Kalita and R. Murugavel

       Ind. J. Chem. 2011, 50A, 763-774

120. Copper phosphates and phosphinates with pyridine/pyrazole alcohol co-ligands: Synthesis and structure. 
R. Pothiraja, M. Sathiyendiran, A. Steiner and R. Murugavel* 

       Inorg. Chim. Acta, 2011, 372, 347-352.

119. Synthesis, spectral characterization, and single crystal X-ray structures of a series of manganese-2,2'-bipyridine complexes derived

       from substituted aromatic carboxylic acids. 
N. Palanisami and R. Murugavel* 

       Inorg. Chim. Acta, 2011, 365, 430-438.



235.  Thermally Labile Organic-Soluble Heterometal Diorganophosphate-Derived Efficient Electrocatalysts for the Oxygen Evolution Reaction

        S Chaudhary, R Murugavel

        Chemistry of Materials,

234.  Hourglass-Shaped Homo-and Heteronuclear Nonanuclear Lanthanide Clusters: Structures, Magnetism, Photoluminescence, and Theoretical Analysis

        P Pandey, D Chauhan, M G Walawalkar, S K Gupta, F Meyer, G Rajaraman, R Murugavel

        Inorganic Chemistry,

233.  Bimetallic Ru (II) Complex Catalysed β‐Alkylation of Secondary Alcohols and α‐Alkylation of Ketones: Selective Formation of              Saturated  Ketones

        G Deshmukh, R Murugavel

        European Journal of Organic Chemistry, e202400131

232.  Converging Hydrogen-Bonded Water Transport Channel with External Magnetic Field in a Janus Molecular Cobalt Phosphate for                   Enhanced Oxygen Evolution Reaction (OER) Activity

        T. Prapakaran, A. Chowdhury, S. Sharma, I. Dwivedi, G. Rajaraman, C. Subramaniam, R. Murugavel

        ACS Materials Letters 6, 2126-2135

231.  Microwave-Assisted Transfer Hydrogenation of Carbonyl and Nitro Compounds Using Bimetallic Ru (II) Cymene Complexes

        G Deshmukh, R Murugavel

        Synlett, DOI: 10.1055/a-2294-1643

230.  Luminescent 8-hydroxyquinoline derived tin (IV) complexes

        P Pandey, MG Walawalkar, R Murugavel

        Journal of Organometallic Chemistry 1007, 123023

229.  Dinuclear Ru (II) Schiff Base Complex Catalyzed One-Pot Synthesis of Quinolines through Acceptorless Dehydrogenative Coupling of             Secondary Alcohols with 2-Nitrobenzyl Alcohol

        G Deshmukh, SJ Gharpure, R Murugavel

        Organometallics,2024, 43, 10, 1190–1202

228.  Carbazole based Schiff base ligand: An efficient “Turn-on/off” sensor for the detection of Al3+ and F− ions and “Turn-off” sensor for             Hg2+ ion

        A Bhanja, P Pandey, R Murugavel

        Journal of Photochemistry and Photobiology A: Chemistry 447, 115269

227.  Hybrid nanoarchitectonics of ordered mesoporous C60–BCN with high surface area for supercapacitors and lithium-ion batteries

        R. Bahadur, G. Singh, Z. Li, B. Singh, R.Srivastava, Y. Sakamoto, S. Chang, R. Murugavel, A. Vinu

        Carbon 216, 118568

226.  Magnetic anisotropy in octahedral Dy (iii) and Yb (iii) complexes

       A Borah, S Dey, K Siddiqui, SK Gupta, G Rajaraman, R Murugavel

        Dalton Transactions 53 (17), 7263-7267

225.  A highly active and chemoselective homobimetallic ruthenium catalyst for one-pot reductive amination in water

        G Deshmukh, TRK Rana, N Yadav, G Rajaraman, R Murugavel

       Green Chemistry 26 (3), 1610-1626


224. Tuning Magnetic Anisotropy in Co (II) Tetrahedral Carbazole-Modified Phosphine Oxide Single-Ion Magnets: Importance of                            Structural Distortion versus Heavy-Ion Effect

        G Bhatt, T Sharma, SK Gupta, F Meyer, G Rajaraman, R Murugavel

        Inorganic Chemistry 62 (46), 18915-18925


118. Assembling Discrete D4R Zeolite SBUs through Noncovalent Interactions. 3. Mediation by Butanols and 1,2-

R. Murugavel*, S. Kuppuswamy, N. Gogoi, and A. Steiner

       Inorg. Chem., 2010, 49, 2153-2162.

117. Noncovalent Synthesis of Hierarchical Zinc Phosphates from a Single Zn4O12P4Double-Four-Ring Building Block: Dimensionality

       Control through the Choice of Auxiliary Ligands. 
R. Murugavel*, S. Kuppuswamy, N. Gogoi, R. Boomishankar and A. Steiner, 

       Chem. Euro. J., 2010, 16, 994-1009.

116. Three-dimensional sodium phosphinates derived from a bis-functionalized phosphinic acid. 
R. Murugavel*, S. Shanmugan and N. Gogoi, 

       Inorg. Chem. Commun., 2010, 13, 1530-1533.

115. A hexanuclear iron(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2]•3CH33CN assembled from 2-hydroxyethyl-3,5-dimethylpyrazole. 
R. Murugavel*, N. Gogoi and R. Clerac, 

       Inorg. Chim. Acta, 2010, 363, 3004-3009.  (Dedicated to Prof. Animesh Chakravorty on his 75th Birthday)

114. One, two, and three methylene phosphonic acid groups (-CH2PO3H2) on a mesitylene ring: synthesis,characterization and aspects of

       supramolecular aggregation. 
R. Murugavel* and M.P. Singh 

       New. J. Chem., 2010, 34, 1846-1854.

113. Rings, chains and cages in metal phosphate chemistry: The interdependence and possible interconversion between various

       structural forms. 
R. Murugavel* and N. Gogoi                   

       . Organomet. Chem., 2010, 695, 916-924.


112. Structural variations in layered alkaline earth metal cyclohexyl phosphonates. 
       R. Murugavel* and N. Gogoi, 

       Bull. Mater. Sci. 2009, 32, 321-328.

111. Nuclearity control in molecular iron phosphates through choice of iron precursors and ancillary ligands. 
       R. Murugavel* and N. Gogoi, 

       Chem. Asian. J., 2009, 4, 923-935. 

110. Solving Zeolite Jigsaw through Coordination Chemistry
       R. Murugavel* and M. P. Singh

       In a Book "Insights into Coordination, Bioinorganic and Applied Inorganic Chemistry"

       Press of Slovak University of Technology, Bratislava,  2009, 211-220.

109. Conformational and Isomeric Preferences of Six-Membered Inorganic Heterocycles [EtNP(E)(OR)]3 (E = Lone Pair, O, S, or Se): A

        Synthetic, Spectroscopic, Structural, and Computational Study. 
        R. Murugavel*, G. Prabusankar, R.J. Butcher, A. Sharma and R.B. Sunoj,  

        Inorg.Chem. 2009, 48, 2048-2059.

108. Tetra- and Decanuclear Iron(III) Phosphonates: Observance of a Rare P-C Bond Cleavage in a Homogeneous Medium. 
        R. Murugavel*, N. Gogoi and R. Clerac, 

        Inorg. Chem., 2009, 48, 646-651.

107. Di-, Tri-, Tetra-, and Hexanuclear Copper(II) Mono-organophosphates: Structure and Nuclearity Dependenceon the Choice of

        Phosphorus Substituents and Auxiliary N-Donor Ligands. 
        R. Murugavel*, S. Kuppuswamy, A.N. Maity and M.P. Singh, 

        Inorg. Chem., 2009, 48, 183-192

106. Controlling the structure of manganese(II) phosphates by the choice and ratio of organophosphate and auxiliary ligands. 
        R. Murugavel*, S. Kuppuswamy, N. Gogoi, A. Steiner and J Bacsa, R. Boomishankar and K.G. Suresh, 

        Chem. Asian. J., 2009, 4, 143-153.



105. Assembling metal phosphonates in the presence of monodentate-terminal and bidentate-bridging pyridine ligands. Use of non-

        covalent and covalent-coordinate interactions to build polymeric metal-phosphonate architectures. 
R. Murugavel* and S. Shanmugan 

        Dalton Trans., 2008, 39, 5358-5367.

104. Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure,Transformations, and

R. Murugavel*, A. Choudhury, M. G. Walawalkar, R. Pothiraja, C. N. R. Rao* 

        Chem.Rev. 2008, 108, 3549-3655.

103. Microwave assisted solid-state synthesis of functional organotin carboxylates from sterically encumbered 3,5-di-tert-butylsalicylic           
R. Murugavel* and N. Gogoi 

        J. Organomet. Chem., 2008, 693, 3111-3116.

102. Organic-Soluble Tri-, Tetra-, and Pentanuclear Titanium(IV) Phosphates. 
R. Murugavel* and S. Kuppuswamy 

        Inorg. Chem., 2008, 47, 7686-7694.

101.  Cooperative Binding of Phosphate Anion and a Neutral Nitrogen Donor to Alkaline-Earth Metal Ions.Investigation of Group 2 Metal-           
Organophosphate Interaction in the Absence and Presence of 1,10-Phenanthroline. 
R. Murugavel*, S. Kuppuswamy and S. Randoll 

        Inorg. Chem., 2008, 47, 6028-6039.

100. Asymmetric pentameric and tetrameric organooxotin clusters: insights into their formation through partial dearylation. 
R. Murugavel* and S. Shanmugan

        Organometallics, 2008, 27, 2784-2788.

99.   Water in organoaluminum chemistry! Three-in-one aluminophosphate clusters that incorporate boehmite repeating units. 
R. Murugavel* and S. Kuppuswamy 

        Chem. Euro. J., 2008, 14, 3869-3873. 

98.   Structural diversity in zinc phosphates and phosphinates: observation of a lattice water dimer sandwiched between phosphoryl

        oxygen atoms. 
R. Pothiraja, S. Shanmugan, M. G. Walawalkar, M. Nethaji, R.J. Butcher and R. Murugavel*

        Eur. J. Inorg. Chem., 2008, 11, 1834-1845. 

97.   Structural diversity in organotin compounds derived from bulky monoaryl phosphates: dimeric, tetrameric, and polymeric tin      

        phosphate complexes. 
R. Murugavel*, S. Shanmugan and S. Kuppuswamy 

        Eur. J. Inorg. Chem., 2008, 9, 1508-1517. 

96.   Facile one-pot synthesis of functionalized organophosphonate esters via ketone insertion into bulky aryl phosphites. 
R. Murugavel* and S. Kuppuswamy 

        J. Chem. Sci. , 2008, 120, 131-136. 


95.   Structural Diversity and Supramolecular Aggregation in Calcium, Strontium, and Barium Salicylates Incorporating 1,10-

        Phenanthroline and 4,4'-Bipyridine: Probing the Softer Side of Group 2 Metal Ions with Pyridinic Ligands. 
R. Murugavel* and R. Korah 

        Inorg. Chem., 2007, 46, 11408-11062.

94.   Supramolecular Aggregation in Alkaline Earth Metal Amino Benzoates with 1,10-Phenanthroline Auxiliary. 
R. Murugavel* and R. Korah

        Synth. React. Inorg. Met.-Org. Chem. Nano-Met. Chem., 2007, 37, 779-795.

93.   A Double Helix Is the Repeating Unit in a Luminescent Calcium 5-Aminoisophthalate Supramolecular Edifice with Water-Filled  

        Hexagonal Channels. 
R. Murugavel*, P. Kumar, M. G. Walawalkar and R. Mathialagan 

        Inorg. Chem., 2007, 46, 6828-6830.  

92.   Unusual reactivity of a sterically hindered diphosphazane ligand, EtN{P(OR)2}2, (R = C6H3(Pri)2-2,6) towards (h3-allyl)palladium

H. Krishna, S.S. Krishnamurthy, M. Nethaji, R. Murugavel* and G. Prabusankar 

        Dalton Trans., 2007, 27, 2908-2914.

91.   Synthesis, magnetic behaviour, and X-ray structures of dinuclear copper complexes with multiple bridges.Efficient and selective

       catalysts for polymerization of 2,6-dimethylphenol. 
R. Murugavel*, R. Pothiraja, N. Gogoi, R. Clerac, L. Lecren, R.J. Butcher, M. Nethaji 

       Dalton Trans., 2007, 23, 2405-2410.

90.  Cobalt-5-aminoisophthalate: [Co(AIPA)(OH2)2]n•nH2O: a new one-dimensional rail-road polymer with occluded water

S. Banerjee, S. Shanmugan and R. Murugavel* 

       Struct. Chem., 2007, 18, 165-169.

89.  First organotin complex of a phosphonic diamide RP(O)(NHR)2. 
R. Murugavel*, R. Pothiraja, S. Shanmugan, N. Singh, R.J. Butcher 

       J. Organomet. Chem., 2007, 692, 1920-1923. 

88.  Seeking tetrameric transition metal phosphonate with a D4R core and organizing it into a 3-D supramolecular assembly. 
R. Murugavel* and S. Shanmugan 

       Chem. Comm., 2007, 12, 1257-1259.


87.  Novel Layered Copper Phosphoramidate, Which Contains Six-Membered Rings Made of Five Different Elements 
R. Murugavel* and M.P. Singh  

       Inorg. Chem., 2006, 45, 9154-9156.
86.  Octameric and decameric aluminophosphates 
R. Murugavel* and S. Kuppuswamy 

       Angew.Chem., Int.Ed., 2006, 45, 7022-7026.

85.  A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu2(HSal)(Sal)(2,2'-bpy)2]

N. Palanisami, G. Prabusankar and R. Murugavel* 

       Inorg. Chem. Commun., 2006, 9, 1002-1006.

84.  Hierarchical structures built form a molecular zinc phosphate core 
R. Murugavel*, S. Kuppuswamy, R. Boomishankar and A. Steiner

       Angew. Chem., Int.Ed., 2006, 45, 5536-5540.

83.  Synthesis and spectral characterization of diorganodiaminosilanes [(ArNH)2SiPhMe] (Ar = 2,6-iPr2C6H3; 2,4,6-Me3C6H2) and lithium          
silylamide [(2,6-Et2C6H3NLi)(2,6-Et2C6H3NH)SiPh2] 
N. Palanisami and R. Murugavel* 

       J. Organomet. Chem., 2006, 691, 3260-3266.

82.  Sterically encumbered acyclic diphosphazanes: synthesis, conformations and coordination behavior 
G. Prabusankar, N. Palanisami, R. Murugavel* and R.J. Butcher 

       Dalton Trans., 2006, 17, 2140-2146. 


81.  First examples of metal cyclohexylphosphonates: influence of the choice of synthetic route on the product 
R. Murugavel*, P. Davis and M. G. Walawalkar 

       Z. Anorg. Allg. Chem., 2005, 631, 2806-2811.

80.  Recent developments in the chemistry of molecular titanosiloxanes and titanophosphonates 
P. Davis and R. Murugavel* 

       Synth. React. Inorg. Met.-Org. Chem. Nano-Met. Chem., 2005, 35, 591-622. 

79.  Non-Interpenetrating Transition Metal Diorganophosphate 2-Dimensional Rectangular Grids from Their 1- Dimensional Wires:

       Structural Transformations under Mild Conditions 
R. Pothiraja, M. Sathiyendiran, R.J. Butcher and R. Murugavel* 

       Inorg. Chem., 2005, 44, 6314-6323.

78.  Synthesis, Spectral Studies, and Structural Characterization of a New Organosilanetriol, Its Amine Complexes, and a Surface Lewis              Basic Cubic Aluminosilicate
G. Prabusankar, R. Murugavel* and R.J. Butcher 

       Organometallics, 2005, 24, 2124-2128. 


77.  Cobalt and Manganese Nets via Their Wires: Facile Transformation in Metal-Diorganophosphates 
R. Pothiraja, M. Sathiyendiran, R.J. Butcher and R. Murugavel* 

       Inorg.Chem., 2004, 43, 7585-7587. 

76.  Hexameric Organotincarboxylates with Cyclic and Drum Structures 
G. Prabusankar and R. Murugavel* 

       Organometallics 2004, 23, 5644-5647. 

75.  Transformations of Molecules and Secondary Building Units to Materials: A Bottom-Up Approach 
 R. Murugavel*, M. G. Walawalkar, M. Dan, H. W. Roesky* and C. N. R. Rao* 

       Acc.Chem.Res. 2004, 37, 763-774.

74.  ATP Synthase and the Torsional Mechanism: Resolving a 50-Yeal-Old Mystery. 
S. Jain, R. Murugavel* and L D. Hansen 

       Curr. Sci., 2004, 87, 16-19 

73.  Polyhedral ferrous and ferric siloxanes 
U.N. Nehete, G. Anantharaman, V. Chandrasekhar, R. Murugavel*, M.G. Walawalkar, H. W. Roesky* , D. Vidovic, J. Magull, K. Samwer

       and B. Sass 

       Angew. Chem., Int. Ed., 2004, 43, 3832-3835. 

72.  Formation of One-Dimensional Water Inside an Organic Solid: Supramolecular Architectures Derived by the Interaction of      

       Aminobenzoic Acids with Nitrogen Bases and H2SO4 
 S. Banerjee and R. Murugavel* 

       Cryst. Growth Des., 2004, 4, 545-552. 

71.   Stabilization of Organosilanetriols in Amine Matrices: Trapping Intermediates between RSi(OH)3 and (RSiO3)3- Anions 
G. Prabusankar, R. Murugavel* and R.J. Butcher

       Organometallics, 2004, 23, 2305-2314. 

70.  Monomeric, Tetrameric, and Polymeric Copper Di-tert-butyl Phosphate Complexes Containing Pyridine Ancillary Ligands 

       R. Murugavel*, M. Sathiyendiran, R. Pothiraja, M. G. Walawalkar, T. Mallah and E. Riviere, 

       Inorg. Chem., 2004, 43, 945-953. 

69.  Stabilization of p-block organoelement terminal hydroxides, thiols, and selenols requires newer synthetic strategies 
 H. W. Roesky*, R. Murugavel and M. G. Walawalkar 

       Chem. Euro. J., 2004, 10, 324-331.


68.  O-H Bond elongation in co-ordinated water through intramolecular P:O•••H-O bonding. Snap-shots' in phosphate ester hydrolysis 
       R. Murugavel*, M. Sathiyendiran, R. Pothiraja and R.J. Butcher 

       Chem. Commun.,  2003, 20, 2546-2547 DOI :10.1039/b306038a

67.  A nanoscopic molecular cadmium phosphonate wrapped in a hydrocarbon sheath 
       G. Anantharaman, M. G. Walawalkar, R. Murugavel, B. Gabor, R. Herbst-Irmer, M. Baldus, B. Angerstein, H. W. Roesky* 

       Angew. Chem., Int.Ed., 2003, 42, 4482-4485 DOI :10.1002/anie.200352133

66.  Reactions of 1,3,5-Benzenetricarboxylic acid with Zn(II) ion in the presence of added amines: Isolation and structure determination

       of zinc coordination polymers with tetrahedral and octahedral zinc centres
       D. Krishnamurthy and R. Murugavel*, 

       Ind. J. Chem., 2003, 42A, 2277-2282. 

65.  Reactivity Studies, Structural Characterization, and Thermolysis of Cubic Titanosiloxanes: Precursors to Titanosilicate Materials

       Which Catalyze Olefin Epoxidation 
       R. Murugavel*, P. Davis and V.S. Shete, 

       Inorg. Chem., 2003, 42, 4696-4706 DOI :10.1021/ic034317m

64.  Synthesis, characterization and structures of diphenyldiaminosilanes bearing bulky substituents on nitrogen 
       R. Murugavel*, N. Palanisami and R.J. Butcher, 

       J. Organomet. Chem., 2003, 675, 65-71 DOI :10.1016/S0022-328X(03)00233-X

63.  Synthesis, spectral characterization and crystal structures of organophosphonic diamides: pyramidal nitrogen centers and hydrogen

       bonding in [PhP(O)(NHtBu)2], [PhP(O)(NHDipp)2] (Dipp = 2,6-iPr2C6H3) and [tBuP(O)(NHiPr)2] 
       R. Murugavel* and R. Pothiraja, New. J. Chem., 2003, 27, 968-974 DOI :10.1039/b300035d

62.  First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)2(H2O)2]n assembly 
       R. Murugavel* and S. Banerjee, 

       Inorg. Chem. Commun., 2003, 6, 810-814 DOI :10.1016/S1387-7003(03)00112-6


61.  Di-tert-butyl Phosphate as Synthon for Metal Phosphate Materials via Single-Source Coordination Polymers [M(dtbp)2]n (M = Mn,  

       Cu) and [Cd(dtbp)2(H2O)]n (dtbp-H = (tBuO)2P(O)OH 
       M. Sathiyendiran and R. Murugavel* Inorg. Chem., 2002, 41, 6404-6411 DOI :10.1021/ic0259787

60.  Anionic metal-organic and cationic organic layer alternation in the coordination polymers [{M(BTEC)(OH2)4]n.n(C4H12N2).4nH2O]n

       (M = Co, Ni, and Zn; BTEC = 1,2,4,5-benzenetetracarboxylate) 
       R. Murugavel*, D. Krishnamurthy and M. Sathiyendiran, J. Chem. Soc., Dalton Trans., 2002, 1, 34-39 DOI :10.1039/b105687p


59.  Some recent developments in Titanium Alkoxide Chemistry 
       R. Murugavel* and P. Davis, 

       Titanium, 2001, 6, 16. 

58.  Reactions of 2-Mercaptobenzoic Acid with Divalent Alkaline Earth Metal Ions: Synthesis, Spectral Studies, and Single-Crystal x-ray

       Structures of Calcium, Strontium, and Barium Complexes of 2,2'-Dithiobis(benzoic acid) 
       R. Murugavel*, K. Baheti and G. Anantharaman, 

       Inorg. Chem., 2001, 40, 6870-6878 DOI :10.1021/ic010519b

57.  Metal containing new inorganic ring systems based on siloxane and phosphazane frameworks 
       R. Murugavel*, G. Prabusankar, V.S. Shete and K. Baheti, 

       Phosphorus, Sulfur, Silicon, 2001, 168-169, 263-268 DOI :10.1080/10426500108546565

56.  Synthesis and characterization of new (chloro)aminosilanes: X-ray crystal structure of [(2,6- Me2C6H3NH)2SiCl2] 

       M. G. Walawalkar and R. Murugavel* Phosphorus, Sulfur, Silicon, 2001, 174, 229-238 

55.  Synthesis of polyferromethylsiloxane sorbents using a sol-gel method 
       Y.L. Zub, H. W. Roesky*, M.M. Malyar, A.A. Chuiko, M. Jaroniec, R. Murugavel 

       Solid State Sciences, 2001, 3, 169-182 DOI :10.1016/S1293-2558(00)01124-9

54.  Synthesis and Structure of a Novel Lithium Gallosiloxane Containing a Ga4Si4O8 Macrocycle Analogous to the S8R Building Unit of

       R. Murugavel*, M.G. Walawalkar, G. Prabusankar & P. Davis. Organometallics 2001, 20, 2639-2642. DOI: 10.1021/om0100636 

53.  A novel cyclic titanasiloxane derived from [Ph2Si(OH)]2O: synthesis and crystal structure of [Cp*Ti(Cl)(OSiPh2OSiPh2OSiPh2O)] 
       R. Murugavel*, V.S. Shete, K. Baheti, P. Davis, 

       J. Organomet. Chem., 2001, 625, 195-199 DOI :10.1016/S0022-328X(00)00946-3

52.  Is Water a Friend or Foe in Organometallic Chemistry? The Case of Group 13 Organometallic Compounds 
       H. W. Roesky*, M. G. Walawalkar andR. Murugavel 

       Acc. Chem. Res., 2001, 34, 201-211 DOI :10.1021/ar0001158

51.  Organic Soluble Silicophosphonate [RSi(OH){OP(O)(H)(OH)}]2O (R = (2,6-i-Pr2C6H3)NSiMe3): The First Silicophosphonate Containing

       Free Si-OH and P-OH Groups 
       R. Murugavel*, G. Prabusankar and M. G. Walawalkar 

       Inorg. Chem., 2001, 40, 1084-1085 DOI :10.1021/ic000960m

50.  Di-tert-butyl Phosphate Complexes of Cobalt(II) and Zinc(II) as Precursors for Ceramic M(PO3)2 and M2P2O7 Materials: Synthesis,  

       Spectral Characterization, Structural Studies, and Role of Auxiliary Ligands 
       R. Murugavel*, M. Sathiyendiran and M. G. Walawalkar 

       Inorg.Chem., 2001, 40, 427-434 DOI :10.1021/ic0006100

49.  Di-tert-butylphosphate complexes of Mn(II) and Cu(II) as single-source precursors for metal phosphate materials 
       R. Murugavel* and M. Sathiyendiran, 

       Chem.Lett., 2001, 1, 84-85. DOI :10.1246/cl.2001.84


48.  Synthetic, spectroscopic, and structural studies on 4-aminobenzoate complexes of divalent alkaline earth metals: X-ray crystal

       structures of [{Mg(H2O)6}(4-aba)2].2H2O and [Ca(4-aba)2(H2O)2] 
       R. Murugavel*, V. V. Karambelkar and G. Anantharaman. Indian J. Chem., (Section A) 2000, 39, 843-850. 

47.  Coordination Polymers of Divalent Metal Ions Based on 1,2,4,5-Benzentetrapolycarboxylic Acid: Synthesis and Structure 
       D. Krishnamurthy, M. Sathiyendiran and R. Murugavel*, 

       Proc. Ind. Acad. Sci. (Chem. Sci.), 2000, 112, 395 

46.  Bulky Aryloxo Organotitanium Chlorides 
       G. Anantharaman, K. Baheti and R. Murugavel*, 

       Proc. Ind. Acad. Sci. (Chem. Sci.), 2000, 112, 373. 

45.  Extended metal-organic solids based on benzenepolycarboxylic and aminobenzoic acids 
       R. Murugavel*, G. Anantharaman, D. Krishnamurthy, M. Sathiyendiran and M. G. Walawalkar

       Proc.Ind. Acad. Sci. (Chem.Sci.), 2000, 112, 273-290 DOI :10.1007/BF02706178

44.  Synthesis, spectral characterization, and structural studies of 2-aminobenzoate complexes of divalent alkaline earth metal ions: x-

       ray crystal structures of [Ca(2-aba)2(OH2)3], [{Sr(2-aba)2(OH2)2}•H2O], and [Ba(2- aba)2(OH2)] (2-abaH = 2-NH2C6H4COOH) 
       R. Murugavel*, V.V. Karambelkar, G. Anantharaman and M. G. Walawalkar

       Inorg.Chem., 2000, 39, 1381-1390 DOI :10.1021/ic990895k


43.  Synthesis and structure of a novel terminal imido complex of titanium 
       B.R. Jagirdar*, R. Murugavel and H. G. Schmidt 

       Inorg. Chim. Acta, 1999, 292, 105-107 DOI :10.1016/S0020-1693(99)00092-4

42.  Molecular titanosiloxanes as model compounds and precursors for titanosilicate materials 
       R. Murugavel*,

       In Advances In Metallo-organic Chemistry, 1999, pp.77-88 (Ed. R. Bohra), RBSA publishers. 

41.  Monovalent Group 13 organometallic compounds: weak association to monomeric, versatile two-electron donors 
       R. Murugavel* and V. Chandrasekhar* 

       Angew. Chem., 1999, 38, 1211-1215 DOI :10.1002/(SICI)1521-3773(19990503)38:9<1211::AID-ANIE1211>3.0.CO;2-O

40.  Molecular Phosphonate Cages: Model Compounds and Starting Materials for Phosphate Materials 
       M. G. Walawalkar, H. W. Roesky* and R. Murugavel. 

       Acc. Chem. Res., 1999, 32, 117-126 DOI :10.1021/AR980040W

39.  Conversion of Alkyltantalum Chlorides to Fluorides Using Trimethyltin Fluoride as a Fluorinating Agent. Crystal Structures of (p-

       MeC6H4CH2)3TaF2, (Me3SnCl•Me3SnF•TaF5)n, (Me3Si)2CHTaCl4,{(Me3Si)2CHTaCl4•[(Me3Si)2CH]2Ta2Cl6(m2-O)}, and (Me3Si)2CHTaF4 
       O.I. Guzyr, M. Schormann, J. Schimkowiak, H. W. Roesky*, C. Lehmann, M. G. Walawalkar, R. Murugavel, H. G. Schmidt and

       M. Noltemeyer, 

       Organometallics, 1999, 18, 832-836. DOI :10.1021/OM980768G

38.  Reactions of Trialkyl Phosphates with Trialkyls of Aluminum and Gallium: New Route to Alumino- and Gallophosphate Compounds

       via Dealkylsilylation 
       J. Pinkas, D. Chakraborty, Y. Yang, R. Murugavel, M. Noltemeyer and H. W. Roesky* Organometallics, 1999, 18, 523-528 

37.  Organosilanetriols: model compounds and potential precursors for metal-containing silicate assemblies 
       R. Murugavel, M. Bhattacharjee and H. W. Roesky* 

       Appl. Organomet. Chem., 1999, 13, 227-243


36.  Gallophosphonates Containing Alkali Metal Ions. 2. Synthesis and Structure of Gallophosphonates Incorporating Na+ and K+ Ions 
       M. G. Walawalkar, R. Murugavel, H. W. Roesky*, I. Uson and R. Kraetzner, 

       Inorg. Chem., 1998, 37, 473-478 DOI :10.1021/IC971441V

35.  Silanetriols: preparation and their reactions 
       R. Murugavel, A. Voight, M. G. Walawalkar and H. W. Roesky* 

       Organosilicon Chemistry III: From Molecules to Materials, (Eds.: N. Auner and J. Weis), VCH, Weinheim, 1998. pp. 376-394

34.  Novel Organic-Soluble Molecular Titanophosphonates with Cage Structures Comparable to Titanium-Containing Silicates 
       M. G. Walawalkar, S. Horchler, S. Dietrich, D. Chakraborty, H. W. Roesky*, M. Schaefer, H. G. Schmidt, G.M. Sheldrick and

       R. Murugavel. 

       Organometallics, 1998, 17, 2865-2868 DOI :10.1021/OM971045K

33.  Synthesis and reactivity of cyclopentadienyl-free organolanthanides: reactions with group 13 complexes 
       S.A.A. Shah, R. Murugavel, H. W. Roesky* and H. G. Schmidt 

       Bull.Polish.Acad.Sci. Chem. 1998, 46, 157-166 


32.  Organometallic Fluorides: Compounds Containing Carbon-Metal-Fluorine Fragments of d-Block Metals 
       E.F. Murphy, R. Murugavel and H. W. Roesky* 

       Chem.Rev.  1997, 97, 3425-3468 DOI :10.1021/CR960365V

31.   Syntheses, spectroscopy and crystal structures of new group 4 metallasiloxanes 
       A. Voight, R. Murugavel, H. W. Roesky* and H. G. Schmidt 

       J.Mol.Struct. 1997, 436-437, 49-57DOI :10.1016/S0022-2860(97)00222-6

30.  Organic-soluble neutral and ionic indium siloxane cages: potential precursors for indium-containing silicates 
       A. Voight, M. G. Walawalkar, R. Murugavel and H. W. Roesky*, E. Parisini and P. Lubini,

       Angew.Chem., 1997, 36, 2203-2205 DOI :10.1002/anie.199722031

29.  Soluble molecular titanosilicates 
       A. Voight, R. Murugavel, M.L. Montero, H. Wessel, F.Q. Liu, , H. W. Roesky*, I. Uson, T. Albers and E. Parisini, 

       Angew. Chem. 1997, 109, 1020-1022; Angew. Chem., Int. Ed. Engl.  1997, 36, 1001-1003 DOI :10.1002/anie.199710011

28.  Titanosilicates: recent developments in synthesis and use as oxidation catalysts 
       R. Murugavel and H. W. Roesky* 

       Angew. Chem., 1997, 109, 491-494; Angew. Chem., Int. Ed. Engl.,  1997, 36, 477-479. DOI :10.1002/anie.199704771

27.  The role of 2,4,6-tris(trifluoromethyl)phenylamino group in stabilizing new phosphorus-, arsenic-, and germanium-containing

       main-group compounds and transition-metal derivatives 
       J.T. Ahlemann, H. W. Roesky*, R. Murugavel, E. Parisini, M. Noltemeyer, H.G. Schmidt, O. Mü R, . Herbst-Irmer, L.N. Leonid ,

       G.Y. Shermolovich, 

       Chem. Ber., 1997, 130, 1113-1121. DOI :10.1002/cber.19971300813

26.  Syntheses, Spectroscopy, Structures, and Reactivity of Neutral Cubic Group 13 Molecular Phosphonates 
       M. G. Walawalkar, R. Murugavel, H. W. Roesky* and H. G. Schmidt 

       Inorg.Chem., 1997, 36, 4202-4207 DOI :10.1021/IC970346J

25.  A Novel Molecular Gallium Phosphonate Cage Containing Sandwiched Lithium Ions: Synthesis, Structure,and Reactivity 
       M. G. Walawalkar, R. Murugavel*, A. Voight, H. W. Roesky and H. G. Schmidt 

       J.Am.Chem.Soc., 1997, 119, 4656-4661 DOI :10.1021/JA964263Y

24.  Organometallic chemistry of C60 beyond λ2-C:C coordination: Buckminsterfullerenes as pentahapto (h5) cyclopentadienyl ligands 
       R. Murugavel* 

       Current Science 1997, 72, 231-232 

23.  The First Molecular Borophosphonate Cage: Synthesis, Spectroscopy, and Single-Crystal X-ray Structure 

       M. G. Walawalkar, R. Murugavel, H. W. Roesky* and H. G. Schmidt 

       Organometallics 1997, 16, 516-518 DOI :10.1021/OM960995N


22. Stannasiloxanes with Acyclic, Bicyclic, and Cubic Core Structures: X-ray Crystal Structure of the Bicyclic Compound [RSi(OSnPh2O)3SiR]       (R = (2,6-Me2C6H3)NSiMe3) 
      A. Voight, R. Murugavel* and H. W. Roesky 

      Organometallics, 1996, 15, 5097-5101 DOI :10.1021/OM960522G

21.  Silanetriols: versatile precursors for new materials 
       M. G. Walawalkar, R. Murugavel and H. W. Roesky* Tailor-Made Silicon-Oxygen Compounds: From Molecules to Materials, 

20.  An efficient synthetic route to primary and secondary condensation products of silanetriols starting from

       R. Murugavel, P. Boettcher, A. Voight, M. G. Walawalkar, H. W. Roesky*, E. Parisini, M. Teichert and M. Noltemeyer, J. Chem. Soc.,        

       Chem. Commun., 1996, 2417-2418. DOI :10.1039/cc9960002417

19.   Infrared and 29Si NMR spectroscopic investigations on metallosiloxanes derived from organosilanetriols 
       A. Voight, R. Murugavel*, U. Ritter and H. W. Roesky J.Organomet.Chem., 1996, 521, 279-286DOI :10.1016/0022-328X(96)06319-X

18.  Organometallic fluorides 
       M. G. Walawalkar, R. Murugavel and H. W. Roesky* 

       Eur.J.Solid State Inorg.Chem., 1996, 33, 943-955

17.   Hetero- and Metallasiloxanes Derived from Silanediols, Disilanols, Silanetriols, and Trisilanols 
       R. Murugavel, A. Voight, M. G. Walawalkar and H. W. Roesky* 

       Chem.Rev., 1996, 96, 2205-2236DOI :10.1021/CR9500747

16.  Cubic Group 13 Heterosiloxanes with Four Co3(CO)9 Cluster Units as Substituents: Novel Soluble Model Compounds for Synthetic

       Zeolites Showing Catalytic Activity in Hydroformylation Reactions 
       U. Ritter, N. Winkhofer, R. Murugavel, A. Voight, D. Stalke and H. W. Roesky* 

       J.Am.Chem.Soc., 1996, 118, 8580-8587 DOI :10.1021/JA952986W

15.   Silanediols derived from silanetriols. X-ray crystal structures of (2,4,6-Me3C6H2)N(SiMe3)Si(OSiMe3)(OH)2 and (2,4,6-

       Me3C6H2)N(SiMe3)Si(OSiMe2R)(OH)2 [R = CH2(2-NH2-3,5-Me2C6H2)] 
       R. Murugavel, A. Voight, V. Chandrasekhar, H. W. Roesky*,H. G. Schmidt and M. Noltemeyer, 

       Chem.Ber., 1996, 129, 391-5 DOI :10.1002/cber.19961290405

14.   Synthesis and structure of gallium siloxane cages: model substances for gallium-containing silicates 
       A. Voight, R. Murugavel*, E. Parisini and H. W. Roesky 

       Angew.Chem., Int.Ed.Engl., 1996, 35, 748-50 DOI :10.1002/anie.199607481

13.   Discrete Silanetriols: Building Blocks for Three-Dimensional Metallasiloxanes 
       R. Murugavel, V. Chandrasekhar and H. W. Roesky* 

       Acc.Chem.Res. , 1996, 29, 183-9 DOI :10.1021/AR950154X

12.   Facile and Rational Route for High-Yield Synthesis of Titanasiloxanes from Aminosilanetriols 
       A. Voight, R. Murugavel, V. Chandrasekhar, N. Winkhofer, H. W. Roesky*, H. G. Schmidt and I. Uson, 

       Organometallics, 1996, 15, 1610-13 DOI :10.1021/OM950816M

11.   Synthesis, spectroscopic and structural characterization of the first mixed fluoro-bromo Group 4 organometallic complex

       [{Cp*ZrF2Br}4] (Cp* = C5Me5) 
       E.F. Murphy, R. Murugavel, H. W. Roesky*, M. Noltemeyer and H. G. Schmidt 

       Z.Anorg.Allg.Chem., 1996, 622, 579-82 

10.  Cyclic and Polyhedral Aluminosiloxanes with Al2Si2O4, Al4Si2O6, and Al4Si4O12Frameworks: X-rayCrystal Structures of [(2,4,6-

       Me3C6H2)N(SiMe3)Si(OAlBu-i)(OAl(Bu-i)2)O]2 and [(2,6-Me2C6H3)N(SiMe3)SiO3Al•C4H8O2]4 
       V. Chandrasekhar, R. Murugavel*, A. Voight, H. W. Roesky, H. G. Schmidt and M. Noltemeyer, 

       Organometallics, 1996, 15, 918-22 DOI :10.1021/OM950685P


9.    New Lipophilic Air-Stable Silanetriols: First Example of an X-ray Crystal Structure of a Silanetriol with Si-N Bonds 
       R. Murugavel, V. Chandrasekhar, A. Voight, H. W. Roesky*, H. G. Schmidt, M. Noltemeyer, 

       Organometallics, 1995, 14, 5298-301 DOI :10.1021/om00011a054

8.    Preparation, spectral characterization, and single crystal x-ray structures of cis and trans isomers of 2,4,6- trifluoroethoxy-1,3,5-

       triethyl-1,3,5,2λ3, 4λ5, 6λ5-triazatriphosphorinane-2,4,6-trioxide, [EtNP(O)(OCH2CF3)]3 
       R. Murugavel*, N. Thirupathi, S.S. Krishnamurthy and M. Nethaji, 

       Heteroatom Chem., 1995, 6, 63-70 DOI :10.1002/hc.520060114

7.    Synthetic, Spectroscopic and Structural Investigations on Cyclic and Acyclic Phosphazanes and their Transition Metal Complexes 
       R. Murugavel. 

       J. Indian. Inst. of Science, 1995, 229-231 


6.    New insights into the chemistry of cyclic phosphorus-nitrogen compounds 
       S. Narasimhamurthy, N. Thirupathi, R. Murugavel and S.S. Krishnamurthy*, 

       Phosphorus, Sulfur, Silicon, 1994, 93-94(1-4), 221-6 DOI :10.1080/10426509408021821

5.    Reactions of the hexachlorocyclodiphosphazane [MeNPCl3]2 with primary aromatic amines: formation of highly basic

       R. Murugavel, S.S. Kumaravel, S.S. Krishnamurthy*, M. Nethaji and J. Chandrasekhar, , 

       J. Chem. Soc., Dalton Trans., 1994, 847-852. DOI :10.1039/DT9940000847


4.    When does a nitrogen attached to a λ3-phosphorus assume a pyramidal geometry? Crystal structures of Group 6 metal carbonyl

       complexes of isomeric forms of λ3-cyclotriphosphazanes 
       R. Murugavel, S.S. Krishnamurthy* and M. Nethaji, J. Chem. Soc., Dalton Trans., 1993, 3635-3639. DOI :10.1039/DT9930003635

3.    Synthesis, spectral characterization and single-crystal structure of a bicyclic tetraphosphapentazane tetraoxide,

       R. Murugavel, S.S. Krishnamurthy* and M. Nethaji, J.Chem.Soc., Dalton Trans., 1993, 2569-73.DOI :10.1039/DT9930002569

2.    Organometallic chemistry of diphosphazanes. Part 7. Platinum(II), palladium-(0), -(I) and -(II) complexes of RN[P(OPh)2]2 (R = Me or        Ph) 
       M.S. Balakrishna, S.S. Krishnamurthy*, R. Murugavel, M. Nethaji and I.I. Mathews, 

       J.Chem.Soc., Dalton Trans.,  1993, 477-82. DOI :10.1039/DT9930000477

1.     Syntheses, spectroscopy, structures, and conformations of l3-cyclotriphosphazanes: role of negative hyperconjugation 
       R. Murugavel, S.S. Krishnamurthy*, J. Chandrasekhar and M. Nethaji, 

       Inorg.Chem.,1993, 32, 5447-53 DOI :10.1021/ic00076a008

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